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- W2331570590 abstract "A persistent triptycenyl sulfenic acid is used as a model for cysteine-derived and other biologically relevant sulfenic acids in experiments which define their redox chemistry. EPR spectroscopy reveals that sulfinyl radicals are persistent and unreactive toward O(2), allowing the O-H bonding dissociation enthalpy (BDE) of the sulfenic acid to be readily determined by equilibration with TEMPO as 71.9 kcal/mol. The E° (RSO•/RSO(-)) and pK(a) of this sulfenic acid are also reported." @default.
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- W2331570590 date "2010-11-04" @default.
- W2331570590 modified "2023-09-30" @default.
- W2331570590 title "The Redox Chemistry of Sulfenic Acids" @default.
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- W2331570590 doi "https://doi.org/10.1021/ja1083046" @default.
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