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• W2331593835 endingPage "16183" @default.
• W2331593835 startingPage "16175" @default.
• W2331593835 abstract "The 4,5-diazafluorenide ligand (L–) serves as an actor ligand in the formal insertion of CO2 into a C–H bond remote from the metal center. With the Ru(II) complex of L– as the starting point, Rh(III), Rh(I), and Cu(I) were used as spectator metal centers to tune the reactivity of the actor ligand toward CO2. In the case of Rh(III)-diazafluorenide a room temperature reversible activation of CO2 was observed, similar to the isoelectronic Ru(II) analogue. In the case of Rh(I)- and Cu(I)-diazafluorenide CO2 is trapped by the formation of dinuclear carboxylate complexes and diazafluorene (LH). The spectator metal center could even be replaced entirely with an organic group allowing for the first metal-free reversible tandem CO2 and C–H activation." @default.
• W2331593835 created "2016-06-24" @default.
• W2331593835 creator A5053688408 @default.
• W2331593835 creator A5069565621 @default.
• W2331593835 creator A5087364188 @default.
• W2331593835 date "2013-10-17" @default.
• W2331593835 modified "2023-09-23" @default.
• W2331593835 title "Tuning the Reactivity of an Actor Ligand for Tandem CO₂and C–H Activations: From Spectator Metals to Metal-Free" @default.
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• W2331593835 doi "https://doi.org/10.1021/ja4073832" @default.
• W2331593835 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24069952" @default.
• W2331593835 hasPublicationYear "2013" @default.
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