FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2331687082> ?p ?o ?g. }

• W2331687082 endingPage "6250" @default.
• W2331687082 startingPage "6232" @default.
• W2331687082 abstract "The phase equilibria of binary CO2 + n-alkane mixtures have been studied by an important number of authors, both experimentally and using different types of thermodynamic models. Modeling studies of the phase behavior of such highly nonideal systems have generally achieved only partially accurate results in the correlation of phase equilibrium data when considering wide ranges of temperature, pressure, and n-alkane molecular weight. In this study, a predictive correlation for the phase behavior of CO2 + n-alkane systems, based on a three-parameter cubic equation of state (EOS), that is, the RK-PR EOS, coupled to cubic mixing rules (CMRs), is developed and tested. CMRs have been shown to be capable of an accurate correlation of the phase equilibria asymmetric CO2 + n-alkane binary systems, in wide ranges of temperature and pressure, when using system-specific interaction parameters. For developing the predictive correlation a critical review of published experimental data for the series was carried out, covering a total of about 100 references. An important degree of inaccuracy or scatter is often found when comparing data sets from different laboratories, specially for the more asymmetric systems (CO2 + a long chain n-alkane). Tables of references covering CO2 + n-alkane systems from C1 to C36 are presented for different types of experimental data, including critical end points (CEPs), critical points, liquid–liquid–vapor (LLV) equilibrium, and isobaric (Txy), isothermal (Pxy), and isoplethic (PT) two-phase equilibrium data sets. Examples of disagreement between different sets of data are presented and discussed. In some cases, a decision concerning the identification of the set that should be regarded as the most reliable, can be based on the experimental method employed, on the purity of the n-alkane, and on the observation of other data for conditions, and/or systems in the series, which are close to those of the data set under scrutiny. Nevertheless, the availability of such information is not enough, in other cases, to assess the quality of a given data set, where we have either different data sets in disagreement or a unique set, for which we are in doubt about its accuracy. In such situation, a predictive correlation for the whole series of binary systems is helpful to make a decision on the possible level of reliability of a given phase equilibrium data set. The present study is useful both to make decisions on conflicts between contradictory phase equilibrium data sets and to predict the phase equilibria of binary systems that have no experimental information available in the literature." @default.
• W2331687082 created "2016-06-24" @default.
• W2331687082 creator A5062981355 @default.
• W2331687082 creator A5074408592 @default.
• W2331687082 creator A5075724908 @default.
• W2331687082 creator A5091269587 @default.
• W2331687082 date "2012-04-23" @default.
• W2331687082 modified "2023-10-16" @default.
• W2331687082 title "Phase Equilibria of CO₂ + <i>n</i>-Alkane Binary Systems in Wide Ranges of Conditions: Development of Predictive Correlations Based on Cubic Mixing Rules" @default.
• W2331687082 cites W101283184 @default.
• W2331687082 cites W1964634295 @default.
• W2331687082 cites W1968538005 @default.
• W2331687082 cites W1976139312 @default.
• W2331687082 cites W1977716488 @default.
• W2331687082 cites W1979495765 @default.
• W2331687082 cites W1984529108 @default.
• W2331687082 cites W1985726741 @default.
• W2331687082 cites W1988849197 @default.
• W2331687082 cites W1990219474 @default.
• W2331687082 cites W2003227387 @default.
• W2331687082 cites W2003361966 @default.
• W2331687082 cites W2016385105 @default.
• W2331687082 cites W2019041154 @default.
• W2331687082 cites W2021482886 @default.
• W2331687082 cites W2021719761 @default.
• W2331687082 cites W2026221843 @default.
• W2331687082 cites W2027784291 @default.
• W2331687082 cites W2034468282 @default.
• W2331687082 cites W2037944664 @default.
• W2331687082 cites W2039099403 @default.
• W2331687082 cites W2039513717 @default.
• W2331687082 cites W2043271798 @default.
• W2331687082 cites W2049436786 @default.
• W2331687082 cites W2053381141 @default.
• W2331687082 cites W2061406738 @default.
• W2331687082 cites W2070281073 @default.
• W2331687082 cites W2074020401 @default.
• W2331687082 cites W2075039605 @default.
• W2331687082 cites W2079190634 @default.
• W2331687082 cites W2081569072 @default.
• W2331687082 cites W2084282247 @default.
• W2331687082 cites W2087225122 @default.
• W2331687082 cites W2092440740 @default.
• W2331687082 cites W2163296854 @default.
• W2331687082 cites W2255827757 @default.
• W2331687082 cites W2481231576 @default.
• W2331687082 cites W27487562 @default.
• W2331687082 cites W4245192217 @default.
• W2331687082 doi "https://doi.org/10.1021/ie2018806" @default.
• W2331687082 hasPublicationYear "2012" @default.
• W2331687082 type Work @default.
• W2331687082 sameAs 2331687082 @default.
• W2331687082 citedByCount "49" @default.
• W2331687082 countsByYear W23316870822013 @default.
• W2331687082 countsByYear W23316870822014 @default.
• W2331687082 countsByYear W23316870822015 @default.
• W2331687082 countsByYear W23316870822016 @default.
• W2331687082 countsByYear W23316870822017 @default.
• W2331687082 countsByYear W23316870822018 @default.
• W2331687082 countsByYear W23316870822019 @default.
• W2331687082 countsByYear W23316870822020 @default.
• W2331687082 countsByYear W23316870822021 @default.
• W2331687082 countsByYear W23316870822022 @default.
• W2331687082 countsByYear W23316870822023 @default.
• W2331687082 crossrefType "journal-article" @default.
• W2331687082 hasAuthorship W2331687082A5062981355 @default.
• W2331687082 hasAuthorship W2331687082A5074408592 @default.
• W2331687082 hasAuthorship W2331687082A5075724908 @default.
• W2331687082 hasAuthorship W2331687082A5091269587 @default.
• W2331687082 hasConcept C121332964 @default.
• W2331687082 hasConcept C121864883 @default.
• W2331687082 hasConcept C133347239 @default.
• W2331687082 hasConcept C134306372 @default.
• W2331687082 hasConcept C138777275 @default.
• W2331687082 hasConcept C146211579 @default.
• W2331687082 hasConcept C178790620 @default.
• W2331687082 hasConcept C182283691 @default.
• W2331687082 hasConcept C185592680 @default.
• W2331687082 hasConcept C2777207669 @default.
• W2331687082 hasConcept C2781327020 @default.
• W2331687082 hasConcept C33923547 @default.
• W2331687082 hasConcept C44280652 @default.
• W2331687082 hasConcept C48372109 @default.
• W2331687082 hasConcept C53810900 @default.
• W2331687082 hasConcept C62520636 @default.
• W2331687082 hasConcept C65559279 @default.
• W2331687082 hasConcept C94375191 @default.
• W2331687082 hasConcept C97355855 @default.
• W2331687082 hasConceptScore W2331687082C121332964 @default.
• W2331687082 hasConceptScore W2331687082C121864883 @default.
• W2331687082 hasConceptScore W2331687082C133347239 @default.
• W2331687082 hasConceptScore W2331687082C134306372 @default.
• W2331687082 hasConceptScore W2331687082C138777275 @default.
• W2331687082 hasConceptScore W2331687082C146211579 @default.
• W2331687082 hasConceptScore W2331687082C178790620 @default.
• W2331687082 hasConceptScore W2331687082C182283691 @default.
• W2331687082 hasConceptScore W2331687082C185592680 @default.
• W2331687082 hasConceptScore W2331687082C2777207669 @default.

• next