Matches in SemOpenAlex for { <https://semopenalex.org/work/W2331706823> ?p ?o ?g. }
- W2331706823 endingPage "1783" @default.
- W2331706823 startingPage "1775" @default.
- W2331706823 abstract "The polymorphic structures of starch were characterized with vibrational sum frequency generation (SFG) spectroscopy. The noncentrosymmetry requirement of SFG spectroscopy allows for the detection of the ordered domains without spectral interferences from the amorphous phase and also the distinction of the symmetric elements among crystalline polymorphs. The V-type amylose was SFG-inactive due to the antiparallel packing of single helices in crystal unit cells, whereas the A- and B-type starches showed strong SFG peaks at 2904 cm–1 and 2952–2968 cm–1, which were assigned to CH stretching of the axial methine group in the ring and CH2 stretching of the exocyclic CH2OH side group, respectively. The CH2/CH intensity ratios of the A- and B-type starches are significantly different, indicating that the conformation of hydroxymethyl groups in these two polymorphs may be different. Cyclodextrin inclusion complexes were also analyzed as a comparison to the V-type amylose and showed that the head-to-tail and head-to-head stacking patterns of cyclodextrin molecules govern their SFG signals and peak positions. Although the molecular packing is different between V-type amylose and cyclodextrin inclusion complexes, both crystals show the annihilation of SFG signals when the functional group dipoles are arranged pointing in opposite directions." @default.
- W2331706823 created "2016-06-24" @default.
- W2331706823 creator A5010293913 @default.
- W2331706823 creator A5025565481 @default.
- W2331706823 creator A5047185875 @default.
- W2331706823 creator A5048614370 @default.
- W2331706823 date "2014-02-06" @default.
- W2331706823 modified "2023-09-30" @default.
- W2331706823 title "Characterization of Starch Polymorphic Structures Using Vibrational Sum Frequency Generation Spectroscopy" @default.
- W2331706823 cites W112088130 @default.
- W2331706823 cites W1496463274 @default.
- W2331706823 cites W1966441205 @default.
- W2331706823 cites W1968141179 @default.
- W2331706823 cites W1973978772 @default.
- W2331706823 cites W1977821983 @default.
- W2331706823 cites W1984914005 @default.
- W2331706823 cites W1987847012 @default.
- W2331706823 cites W1992899652 @default.
- W2331706823 cites W1993920583 @default.
- W2331706823 cites W1996442036 @default.
- W2331706823 cites W1998900641 @default.
- W2331706823 cites W2004354822 @default.
- W2331706823 cites W2005831296 @default.
- W2331706823 cites W2009653736 @default.
- W2331706823 cites W2011221474 @default.
- W2331706823 cites W2016655960 @default.
- W2331706823 cites W2026432961 @default.
- W2331706823 cites W2028628363 @default.
- W2331706823 cites W2031017149 @default.
- W2331706823 cites W2038001685 @default.
- W2331706823 cites W2038781049 @default.
- W2331706823 cites W2038900003 @default.
- W2331706823 cites W2040444701 @default.
- W2331706823 cites W2041198130 @default.
- W2331706823 cites W2044116573 @default.
- W2331706823 cites W2048420229 @default.
- W2331706823 cites W2048553924 @default.
- W2331706823 cites W2053420181 @default.
- W2331706823 cites W2054920313 @default.
- W2331706823 cites W2061062287 @default.
- W2331706823 cites W2063173197 @default.
- W2331706823 cites W2067507582 @default.
- W2331706823 cites W2070462654 @default.
- W2331706823 cites W2070928722 @default.
- W2331706823 cites W2073205691 @default.
- W2331706823 cites W2073844716 @default.
- W2331706823 cites W2079043984 @default.
- W2331706823 cites W2089403603 @default.
- W2331706823 cites W2089711603 @default.
- W2331706823 cites W2109027740 @default.
- W2331706823 cites W2111526375 @default.
- W2331706823 cites W2125799286 @default.
- W2331706823 cites W2136612808 @default.
- W2331706823 cites W2159783127 @default.
- W2331706823 cites W2161970226 @default.
- W2331706823 cites W21904020 @default.
- W2331706823 cites W2313728162 @default.
- W2331706823 cites W2321483341 @default.
- W2331706823 cites W2324624147 @default.
- W2331706823 cites W2325556119 @default.
- W2331706823 doi "https://doi.org/10.1021/jp411130n" @default.
- W2331706823 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24432980" @default.
- W2331706823 hasPublicationYear "2014" @default.
- W2331706823 type Work @default.
- W2331706823 sameAs 2331706823 @default.
- W2331706823 citedByCount "77" @default.
- W2331706823 countsByYear W23317068232014 @default.
- W2331706823 countsByYear W23317068232015 @default.
- W2331706823 countsByYear W23317068232016 @default.
- W2331706823 countsByYear W23317068232017 @default.
- W2331706823 countsByYear W23317068232018 @default.
- W2331706823 countsByYear W23317068232019 @default.
- W2331706823 countsByYear W23317068232020 @default.
- W2331706823 countsByYear W23317068232021 @default.
- W2331706823 countsByYear W23317068232022 @default.
- W2331706823 countsByYear W23317068232023 @default.
- W2331706823 crossrefType "journal-article" @default.
- W2331706823 hasAuthorship W2331706823A5010293913 @default.
- W2331706823 hasAuthorship W2331706823A5025565481 @default.
- W2331706823 hasAuthorship W2331706823A5047185875 @default.
- W2331706823 hasAuthorship W2331706823A5048614370 @default.
- W2331706823 hasConcept C115260700 @default.
- W2331706823 hasConcept C121332964 @default.
- W2331706823 hasConcept C142089489 @default.
- W2331706823 hasConcept C153642686 @default.
- W2331706823 hasConcept C158622935 @default.
- W2331706823 hasConcept C160018778 @default.
- W2331706823 hasConcept C178790620 @default.
- W2331706823 hasConcept C185592680 @default.
- W2331706823 hasConcept C2776804113 @default.
- W2331706823 hasConcept C2777207611 @default.
- W2331706823 hasConcept C2780591741 @default.
- W2331706823 hasConcept C32891209 @default.
- W2331706823 hasConcept C33347731 @default.
- W2331706823 hasConcept C529335014 @default.
- W2331706823 hasConcept C62520636 @default.
- W2331706823 hasConcept C71240020 @default.
- W2331706823 hasConcept C78854221 @default.