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- W2331716838 abstract "Abstract Solvent extraction of microamounts of trivalent europium and americium into nitrobenzene by using a mixture of hydrogen dicarbollylcobaltate (H + B − ) and magnesium ionophore II (L) was studied. The equilibrium data were explained assuming that the species HL + , <m:math xmlns:m=http://www.w3.org/1998/Math/MathML display=inline> <m:mrow> <m:mtext>H</m:mtext> <m:msubsup> <m:mtext>L</m:mtext> <m:mn>2</m:mn> <m:mo>+</m:mo> </m:msubsup> </m:mrow> </m:math> ${rm{HL}}_2^ + $ , <m:math xmlns:m=http://www.w3.org/1998/Math/MathML display=inline> <m:mrow> <m:mtext>M</m:mtext> <m:msubsup> <m:mtext>L</m:mtext> <m:mn>2</m:mn> <m:mrow> <m:mn>3</m:mn> <m:mo>+</m:mo> </m:mrow> </m:msubsup> </m:mrow> </m:math> ${rm{ML}}_2^{3 + }$ , and <m:math xmlns:m=http://www.w3.org/1998/Math/MathML> <m:mrow> <m:mtext>M</m:mtext> <m:msubsup> <m:mtext>L</m:mtext> <m:mn>3</m:mn> <m:mrow> <m:mn>3</m:mn> <m:mo>+</m:mo> </m:mrow> </m:msubsup> </m:mrow> </m:math> ${rm{ML}}_3^{3 + }$ (M 3+ = Eu 3+ , Am 3+ ; L=magnesium, ionophore II) are extracted into the nitrobenzene phase. Extraction and stability constants of the cationic complex species in nitrobenzene saturated with water were determined and discussed. From the experimental results it is evident that this effective magnesium ionophore II receptor for the Eu 3+ and Am 3+ cations could be considered as a potential extraction agent for nuclear waste treatment." @default.
- W2331716838 created "2016-06-24" @default.
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- W2331716838 date "2016-04-07" @default.
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- W2331716838 title "Magnesium ionophore II as an extraction agent for trivalent europium and americium" @default.
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- W2331716838 doi "https://doi.org/10.1515/ract-2015-2500" @default.
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