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• W2331746987 abstract "High-density polynorbornene azobenzene liquid-crystalline brushes are synthesized on quartz substrates by surface-initiated ring-opening metathesis polymerization (SI-ROMP) using Grubbs third-generation catalyst. The grafting process is controlled over the thickness of the brush from a solid-supported substrate in a stoichiometric manner. A highly ordered liquid-crystal arrangement was formed for such brushes as revealed by spectroscopic measurements and grazing angle X-ray diffraction analysis. Marked features of this method in the structure and photoalignment behavior are unveiled by comparison with brushes made by surface-initiated atom-transfer radical polymerization (SI-ATRP)." @default.
• W2331746987 created "2016-06-24" @default.
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• W2331746987 date "2013-06-05" @default.
• W2331746987 modified "2023-09-28" @default.
• W2331746987 title "High-Density Liquid-Crystalline Azobenzene Polymer Brush Attained by Surface-Initiated Ring-Opening Metathesis Polymerization" @default.
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• W2331746987 doi "https://doi.org/10.1021/la4002847" @default.
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