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- W2331915526 abstract "Abstract In this paper we report the synthesis method and the structure of a one-dimensional thiocyanato bridged heterometallic compound, [Cu(en)2Zn(NCS)4]⋅H2O (1). Moreover, we compare the structure of (1) with the previously described structures of [Cu(en)2Zn(NCS)4]⋅0.5H2O (2) and [Cu(en)2Zn(NCS)4]⋅CH3CN (3) Pryma et al. (2003) [7]. The compound (1) has been characterized by thermal decomposition, IR, Vis and EPR spectra, and magnetic studies. Structure has been determined by X-ray analysis. Described coordination polymer crystallizes in the orthorhombic Cmcm space group with a = 12.414(2), b = 10.3276(14), c = 14.967(2) A, α = β = γ = 90°, V = 1918.8(5) A3 and Z = 4. Each distorted tetrahedral zinc(II) centre (with N-bonded NCS−) links two tetragonally distorted octahedral copper(II) centres by two end-to-end thiocyanato bridges and vice versa forming a zigzag type of CuZn chain. The structures of (1), (2) and (3) differ in crystallographic system, space group and/or CuZn chain type as well as in details. Variable temperature magnetic susceptibility measurements show very weak antiferromagnetic interactions between the paramagnetic copper(II) ions for compound (1)." @default.
- W2331915526 created "2016-06-24" @default.
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- W2331915526 date "2015-03-01" @default.
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- W2331915526 title "Synthesis, characterization and crystal structure of a 1D thiocyanato bridged [Cu(en)2Zn(NCS)4]⋅H2O. Comparison of the three structures with the same [Cu(en)2Zn(NCS)4] unit − different in structural terms" @default.
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- W2331915526 doi "https://doi.org/10.1016/j.molstruc.2014.11.022" @default.
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