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- W2331996364 abstract "Wollastonite (β-CaSiO3) was synthesized by the TW method from the mixed solutions of Si(C2H5)4 and CaC12 with both the small amount of 2M-HC1 as catalyst and separately the desired quantity of each aqueous solution made up of additives such as MnC12, FeC13, NiC12 or CuC12. In the case of the sample obtained without the additives, pure β-CaSi03 in a single phase was not obtained at any heat treatment temperature of this study. The acceleration effects of additives on the formation of β-CaSiO3 were arranged in the order of MnC12 > NiC12 > CuC12 > FeC13 at the temperature of 1100°C. MnC12 was most effective for the acceleration of β-CaSiO3 formation among the additives, and in the case of each sample obtained with the addition of MnCl2 with 7.8 × 10-3 mole or 9.3 × 10-3 mole, pure β-CaSiO3 in single phase was obtained at 1100°C. It was thought that β-CaSiO3 was formed by reaction of β-Cristobalite with Ca3Si2O7, simultaneously according to the phase transition from α-CaSiO3 to β-CaSiO3." @default.
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- W2331996364 date "2003-01-01" @default.
- W2331996364 modified "2023-09-27" @default.
- W2331996364 title "Effect of Transition Metal Chlorides on the Formation of .BETA.-CaSiO3 by the TW Method" @default.
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- W2331996364 doi "https://doi.org/10.2497/jjspm.50.664" @default.
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