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- W2332007835 abstract "We synthesized for the first time a series of emissive ring-shaped Re(I) complexes (Re-rings) with various numbers of Re(I) units and various lengths of bridge ligands. The photophysical properties of the Re-rings could be varied widely through changes in the size of the central cavity. A smaller central cavity of the Re-rings induced intramolecular π–π interactions between the ligands and consequently caused a stronger emission and a longer lifetime of the excited state. The Re-rings can function as efficient and durable photosensitizers. The combination of a trinuclear Re-ring photosensitizer with fac-[Re(bpy)(CO)3(MeCN)]+ (bpy = 2,2′-bipyridine) as a catalyst photocatalyzed CO2 reduction with the highest quantum yield of 82%." @default.
- W2332007835 created "2016-06-24" @default.
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- W2332007835 date "2013-08-27" @default.
- W2332007835 modified "2023-09-30" @default.
- W2332007835 title "Ring-Shaped Re(I) Multinuclear Complexes with Unique Photofunctional Properties" @default.
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- W2332007835 doi "https://doi.org/10.1021/ja406144h" @default.
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