Matches in SemOpenAlex for { <https://semopenalex.org/work/W2332096090> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2332096090 abstract "The methyltriphenylphosphonium methylcarbonate salt [Ph3PCH3][CH3OCO2], obtained directly by quaternarization of triphenylphosphine with dimethylcarbonate, is a latent ylide that promotes Wittig vinylation of aldehydes and ketones. Alkenes are obtained simply by mixing [Ph3PCH3][CH3OCO2] and the carbonyl and heating in a solvent (no base, no halides, and no inorganic byproducts). Deuterium exchange experiments and the particularly short anion-cation distance measured by XRD in [Ph3PCH3][CH3OCO2] allowed to explain the nature and reactivity of this species. Green chemistry metrics (atom economy, mass index, environmental factor) indicate that this vinylation procedure is more efficient than comparable ones. Deuterated [Ph3PCD3][CH3OCO2] promoted the synthesis of deuterated olefins." @default.
- W2332096090 created "2016-06-24" @default.
- W2332096090 creator A5024496469 @default.
- W2332096090 creator A5048020885 @default.
- W2332096090 creator A5056186703 @default.
- W2332096090 creator A5086358403 @default.
- W2332096090 creator A5087449574 @default.
- W2332096090 date "2016-03-01" @default.
- W2332096090 modified "2023-10-05" @default.
- W2332096090 title "ChemInform Abstract: Methyltriphenylphosphonium Methylcarbonate, an All-In-One Wittig Vinylation Reagent." @default.
- W2332096090 cites W2162547008 @default.
- W2332096090 doi "https://doi.org/10.1002/chin.201616058" @default.
- W2332096090 hasPublicationYear "2016" @default.
- W2332096090 type Work @default.
- W2332096090 sameAs 2332096090 @default.
- W2332096090 citedByCount "0" @default.
- W2332096090 crossrefType "journal-article" @default.
- W2332096090 hasAuthorship W2332096090A5024496469 @default.
- W2332096090 hasAuthorship W2332096090A5048020885 @default.
- W2332096090 hasAuthorship W2332096090A5056186703 @default.
- W2332096090 hasAuthorship W2332096090A5086358403 @default.
- W2332096090 hasAuthorship W2332096090A5087449574 @default.
- W2332096090 hasConcept C121332964 @default.
- W2332096090 hasConcept C139872579 @default.
- W2332096090 hasConcept C142724271 @default.
- W2332096090 hasConcept C155647269 @default.
- W2332096090 hasConcept C161790260 @default.
- W2332096090 hasConcept C171560689 @default.
- W2332096090 hasConcept C178790620 @default.
- W2332096090 hasConcept C185592680 @default.
- W2332096090 hasConcept C204787440 @default.
- W2332096090 hasConcept C24292678 @default.
- W2332096090 hasConcept C2776910235 @default.
- W2332096090 hasConcept C2777247709 @default.
- W2332096090 hasConcept C2779167645 @default.
- W2332096090 hasConcept C2780471494 @default.
- W2332096090 hasConcept C40875361 @default.
- W2332096090 hasConcept C58364064 @default.
- W2332096090 hasConcept C62520636 @default.
- W2332096090 hasConcept C71924100 @default.
- W2332096090 hasConceptScore W2332096090C121332964 @default.
- W2332096090 hasConceptScore W2332096090C139872579 @default.
- W2332096090 hasConceptScore W2332096090C142724271 @default.
- W2332096090 hasConceptScore W2332096090C155647269 @default.
- W2332096090 hasConceptScore W2332096090C161790260 @default.
- W2332096090 hasConceptScore W2332096090C171560689 @default.
- W2332096090 hasConceptScore W2332096090C178790620 @default.
- W2332096090 hasConceptScore W2332096090C185592680 @default.
- W2332096090 hasConceptScore W2332096090C204787440 @default.
- W2332096090 hasConceptScore W2332096090C24292678 @default.
- W2332096090 hasConceptScore W2332096090C2776910235 @default.
- W2332096090 hasConceptScore W2332096090C2777247709 @default.
- W2332096090 hasConceptScore W2332096090C2779167645 @default.
- W2332096090 hasConceptScore W2332096090C2780471494 @default.
- W2332096090 hasConceptScore W2332096090C40875361 @default.
- W2332096090 hasConceptScore W2332096090C58364064 @default.
- W2332096090 hasConceptScore W2332096090C62520636 @default.
- W2332096090 hasConceptScore W2332096090C71924100 @default.
- W2332096090 hasLocation W23320960901 @default.
- W2332096090 hasOpenAccess W2332096090 @default.
- W2332096090 hasPrimaryLocation W23320960901 @default.
- W2332096090 hasRelatedWork W1966008039 @default.
- W2332096090 hasRelatedWork W1976250841 @default.
- W2332096090 hasRelatedWork W2009925624 @default.
- W2332096090 hasRelatedWork W2018626136 @default.
- W2332096090 hasRelatedWork W2051156996 @default.
- W2332096090 hasRelatedWork W2090870924 @default.
- W2332096090 hasRelatedWork W2111294834 @default.
- W2332096090 hasRelatedWork W2129480882 @default.
- W2332096090 hasRelatedWork W2139939973 @default.
- W2332096090 hasRelatedWork W2949421070 @default.
- W2332096090 hasRelatedWork W2949719319 @default.
- W2332096090 hasRelatedWork W2949731853 @default.
- W2332096090 hasRelatedWork W2950675345 @default.
- W2332096090 hasRelatedWork W2951052210 @default.
- W2332096090 hasRelatedWork W2951650368 @default.
- W2332096090 hasRelatedWork W2952028426 @default.
- W2332096090 hasRelatedWork W2952256242 @default.
- W2332096090 hasRelatedWork W2952745893 @default.
- W2332096090 hasRelatedWork W2952794897 @default.
- W2332096090 hasRelatedWork W2953238038 @default.
- W2332096090 isParatext "false" @default.
- W2332096090 isRetracted "false" @default.
- W2332096090 magId "2332096090" @default.
- W2332096090 workType "article" @default.