FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2332099705> ?p ?o ?g. }

• W2332099705 endingPage "6039" @default.
• W2332099705 startingPage "6031" @default.
• W2332099705 abstract "Four model compounds and four dipeptides containing N-aminoazetidinecarboxylic acid (AAzC) and a particular stereoisomer of 2-aminocyclobutanecarboxylic acid (ACBC) were studied to establish their solution state conformational preferences, particularly regarding the ability of AAzC to induce a three-center hydrogen-bonded folding feature known as a “hydrazino turn”. On the basis of IR and NMR experiments, supported by molecular modeling, the AAzC residue adopted a trans configuration amenable to the formation of a cyclic eight-membered hydrogen bond conformation in solution, in all cases studied. The implication of the heterocyclic nitrogen atom of AAzC in the trans-like structure was demonstrated via a refined 1H–15N HMBC experiment giving exploitable data at natural 15N isotopic abundance, providing unprecedented evidence for the solution state hydrazino turn conformation. The predominance of this secondary structural feature depended on the configuration of the neighboring ACBC residue in the dipeptides: while the trans-ACBC derivatives prefer the hydrazino turn, the cis-ACBC derivatives may also populate low-energy 10-membered hydrogen-bonded ring structures. X-ray diffraction analysis of three compounds confirmed the presence of a solid state hydrazino turn in two cases, with geometries similar to those deduced from the solution state studies, but in the third compound, no intramolecular hydrogen-bonding feature was in evidence." @default.
• W2332099705 created "2016-06-24" @default.
• W2332099705 creator A5029005332 @default.
• W2332099705 creator A5043590923 @default.
• W2332099705 creator A5059418406 @default.
• W2332099705 creator A5060105631 @default.
• W2332099705 creator A5073226840 @default.
• W2332099705 creator A5075694197 @default.
• W2332099705 creator A5080098073 @default.
• W2332099705 date "2013-06-07" @default.
• W2332099705 modified "2023-10-18" @default.
• W2332099705 title "Solution State Conformational Preferences of Dipeptides Derived from <i>N</i>-Aminoazetidinecarboxylic Acid: An Assessment of the Hydrazino Turn" @default.
• W2332099705 cites W1963551721 @default.
• W2332099705 cites W1969044324 @default.
• W2332099705 cites W1977064591 @default.
• W2332099705 cites W1982484944 @default.
• W2332099705 cites W1986326797 @default.
• W2332099705 cites W1988531810 @default.
• W2332099705 cites W1989845887 @default.
• W2332099705 cites W1992281228 @default.
• W2332099705 cites W1996694098 @default.
• W2332099705 cites W2011171311 @default.
• W2332099705 cites W2011217627 @default.
• W2332099705 cites W2011880152 @default.
• W2332099705 cites W2028029903 @default.
• W2332099705 cites W2028760518 @default.
• W2332099705 cites W2031525026 @default.
• W2332099705 cites W2032418083 @default.
• W2332099705 cites W2032891742 @default.
• W2332099705 cites W2036290134 @default.
• W2332099705 cites W2039517444 @default.
• W2332099705 cites W2044667596 @default.
• W2332099705 cites W2055389105 @default.
• W2332099705 cites W2062163199 @default.
• W2332099705 cites W2069410927 @default.
• W2332099705 cites W2073221676 @default.
• W2332099705 cites W2075257695 @default.
• W2332099705 cites W2082402004 @default.
• W2332099705 cites W2082736290 @default.
• W2332099705 cites W2083035513 @default.
• W2332099705 cites W2083787723 @default.
• W2332099705 cites W2086167852 @default.
• W2332099705 cites W2090923413 @default.
• W2332099705 cites W2096649736 @default.
• W2332099705 cites W2109149713 @default.
• W2332099705 cites W2116709645 @default.
• W2332099705 cites W2120901082 @default.
• W2332099705 cites W2131505590 @default.
• W2332099705 cites W2134677766 @default.
• W2332099705 cites W2146215891 @default.
• W2332099705 cites W2157469299 @default.
• W2332099705 cites W2169821755 @default.
• W2332099705 cites W2171011232 @default.
• W2332099705 cites W2322676564 @default.
• W2332099705 cites W2329064054 @default.
• W2332099705 cites W2333137980 @default.
• W2332099705 cites W2334928987 @default.
• W2332099705 cites W2394803363 @default.
• W2332099705 cites W4234803768 @default.
• W2332099705 cites W4248737905 @default.
• W2332099705 doi "https://doi.org/10.1021/jo400736t" @default.
• W2332099705 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23692347" @default.
• W2332099705 hasPublicationYear "2013" @default.
• W2332099705 type Work @default.
• W2332099705 sameAs 2332099705 @default.
• W2332099705 citedByCount "16" @default.
• W2332099705 countsByYear W23320997052014 @default.
• W2332099705 countsByYear W23320997052015 @default.
• W2332099705 countsByYear W23320997052016 @default.
• W2332099705 countsByYear W23320997052017 @default.
• W2332099705 countsByYear W23320997052018 @default.
• W2332099705 countsByYear W23320997052019 @default.
• W2332099705 countsByYear W23320997052020 @default.
• W2332099705 crossrefType "journal-article" @default.
• W2332099705 hasAuthorship W2332099705A5029005332 @default.
• W2332099705 hasAuthorship W2332099705A5043590923 @default.
• W2332099705 hasAuthorship W2332099705A5059418406 @default.
• W2332099705 hasAuthorship W2332099705A5060105631 @default.
• W2332099705 hasAuthorship W2332099705A5073226840 @default.
• W2332099705 hasAuthorship W2332099705A5075694197 @default.
• W2332099705 hasAuthorship W2332099705A5080098073 @default.
• W2332099705 hasConcept C112887158 @default.
• W2332099705 hasConcept C178790620 @default.
• W2332099705 hasConcept C185592680 @default.
• W2332099705 hasConcept C2780378348 @default.
• W2332099705 hasConcept C2781338088 @default.
• W2332099705 hasConcept C32909587 @default.
• W2332099705 hasConcept C55493867 @default.
• W2332099705 hasConcept C71240020 @default.
• W2332099705 hasConcept C75079739 @default.
• W2332099705 hasConcept C85641259 @default.
• W2332099705 hasConceptScore W2332099705C112887158 @default.
• W2332099705 hasConceptScore W2332099705C178790620 @default.
• W2332099705 hasConceptScore W2332099705C185592680 @default.
• W2332099705 hasConceptScore W2332099705C2780378348 @default.
• W2332099705 hasConceptScore W2332099705C2781338088 @default.
• W2332099705 hasConceptScore W2332099705C32909587 @default.
• W2332099705 hasConceptScore W2332099705C55493867 @default.

• next