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• W2332150138 endingPage "4542" @default.
• W2332150138 startingPage "4531" @default.
• W2332150138 abstract "Six transition-metal arene complexes containing alkynylsilyl groups have been synthesized. Direct complexation of the corresponding arenes yielded the alkynylsilylarene complexes PhC≡CMe2SiPhCr(CO)3 (1), n-PrC≡CMe2SiPhCr(CO)3 (2), n-PrC≡CMe2Si–SiMe2–SiMe2PhCr(CO)3 (4), and PhC≡CMe2SiPhMo(CO)3 (6), while PhC≡CMe2Si–SiMe2PhCr(CO)3 (3) and (PhC≡CMe2SiPh)2Cr (7) were synthesized by modification of precomplexed arenes. The reactivity of the C≡C triple bonds of the synthesized alkynylsilyl compounds toward complexation and carbon–carbon bond-forming reactions was studied. The alkynyl groups of 1 and 6 underwent intermolecular complexation to yield the trinuclear compounds 1·Ni2Cp2 (8) and 6·Cp2Mo2(CO)4 (9), respectively, while reaction of 7 with CpCo(PPh3)2 led to intramolecular [2 + 2] cycloaddition of its two alkynyl groups with formation of the dinuclear cyclobutadiene complex CpCo(PhCCSiMe2Ph)2Cr (10). All of these complexes were characterized by NMR, IR, and mostly also UV/vis (1, 2, 6–10) spectroscopy. The molecular and crystal structures of compounds 1, 2, and 6–10 were determined by single-crystal X-ray diffraction." @default.
• W2332150138 created "2016-06-24" @default.
• W2332150138 creator A5005708838 @default.
• W2332150138 creator A5038071984 @default.
• W2332150138 creator A5060904103 @default.
• W2332150138 date "2013-08-15" @default.
• W2332150138 modified "2023-10-16" @default.
• W2332150138 title "Transition-Metal Complexes Containing Alkynylsilyl Functionalized η⁶-Arene Ligands" @default.
• W2332150138 cites W1500103380 @default.
• W2332150138 cites W1517086895 @default.
• W2332150138 cites W1517125669 @default.
• W2332150138 cites W1546150330 @default.
• W2332150138 cites W1549583922 @default.
• W2332150138 cites W1597674223 @default.
• W2332150138 cites W1966626313 @default.
• W2332150138 cites W1973160630 @default.
• W2332150138 cites W1974937831 @default.
• W2332150138 cites W1975874921 @default.
• W2332150138 cites W1975990029 @default.
• W2332150138 cites W1976206541 @default.
• W2332150138 cites W1985060707 @default.
• W2332150138 cites W1985851792 @default.
• W2332150138 cites W1985978261 @default.
• W2332150138 cites W1986999544 @default.
• W2332150138 cites W1988734156 @default.
• W2332150138 cites W1992664136 @default.
• W2332150138 cites W1993506030 @default.
• W2332150138 cites W1998627746 @default.
• W2332150138 cites W1999011155 @default.
• W2332150138 cites W2002866394 @default.
• W2332150138 cites W2004776182 @default.
• W2332150138 cites W2007267757 @default.
• W2332150138 cites W2008159077 @default.
• W2332150138 cites W2010576408 @default.
• W2332150138 cites W2012749695 @default.
• W2332150138 cites W2013641647 @default.
• W2332150138 cites W2014737812 @default.
• W2332150138 cites W2016933774 @default.
• W2332150138 cites W2018549185 @default.
• W2332150138 cites W2019061190 @default.
• W2332150138 cites W2023376047 @default.
• W2332150138 cites W2026153116 @default.
• W2332150138 cites W2026437691 @default.
• W2332150138 cites W2028789456 @default.
• W2332150138 cites W2029259254 @default.
• W2332150138 cites W2029367096 @default.
• W2332150138 cites W2030907443 @default.
• W2332150138 cites W2034142756 @default.
• W2332150138 cites W2034578247 @default.
• W2332150138 cites W2036260939 @default.
• W2332150138 cites W2043335668 @default.
• W2332150138 cites W2045169537 @default.
• W2332150138 cites W2048787686 @default.
• W2332150138 cites W2051090872 @default.
• W2332150138 cites W2053600239 @default.
• W2332150138 cites W2055301818 @default.
• W2332150138 cites W2056349155 @default.
• W2332150138 cites W2058916692 @default.
• W2332150138 cites W2061714952 @default.
• W2332150138 cites W2061821342 @default.
• W2332150138 cites W2067354575 @default.
• W2332150138 cites W2074077158 @default.
• W2332150138 cites W2074495652 @default.
• W2332150138 cites W2077543087 @default.
• W2332150138 cites W2078089048 @default.
• W2332150138 cites W2078773978 @default.
• W2332150138 cites W2079038159 @default.
• W2332150138 cites W2080017141 @default.
• W2332150138 cites W2080948524 @default.
• W2332150138 cites W2083666754 @default.
• W2332150138 cites W2085648584 @default.
• W2332150138 cites W2086809313 @default.
• W2332150138 cites W2088481620 @default.
• W2332150138 cites W2095221252 @default.
• W2332150138 cites W2096402434 @default.
• W2332150138 cites W2112081360 @default.
• W2332150138 cites W2116169853 @default.
• W2332150138 cites W2117005320 @default.
• W2332150138 cites W2120120698 @default.
• W2332150138 cites W2120657946 @default.
• W2332150138 cites W2131350133 @default.
• W2332150138 cites W2140945788 @default.
• W2332150138 cites W2144109631 @default.
• W2332150138 cites W2148066840 @default.
• W2332150138 cites W2158504892 @default.
• W2332150138 cites W2317609127 @default.
• W2332150138 cites W2321050205 @default.
• W2332150138 cites W2329023490 @default.
• W2332150138 cites W2949351373 @default.
• W2332150138 cites W2951162085 @default.
• W2332150138 cites W2953200133 @default.
• W2332150138 cites W3004427708 @default.
• W2332150138 cites W3004710398 @default.
• W2332150138 cites W4229738157 @default.
• W2332150138 cites W4241597807 @default.
• W2332150138 cites W4242702253 @default.
• W2332150138 cites W4245677282 @default.
• W2332150138 cites W66690506 @default.

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