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• W2332164467 endingPage "1421" @default.
• W2332164467 startingPage "1409" @default.
• W2332164467 abstract "Polarized synchrotron-based attenuated total-reflection infrared (ATR–IR) spectra of crystals of natural zircon of various origins and degree of disorder are reported. We demonstrate the potential of ATR–IR microspectroscopy for non-destructive structural analysis of zircon microcrystals. Disorder-related IR absorption at wavenumbers lower than the bands arising from the fundamental A 2u [ν 3 (SiO 4 )] and E u [ν 3 (SiO 4 )] zircon modes was observed, which reveals the existence of spatial regions with abundant SiO 4 tetrahedra with longer bonds. A pronounced peak near 990 cm −1 is indicative of an abundance of polymerized SiO 4 tetrahedra. Weak signals in the range 1050–1250 cm −1 show connectivity defects (broken Si–O–Zr bridges) and the existence of shorter Si–O bonds." @default.
• W2332164467 created "2016-06-24" @default.
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• W2332164467 date "2010-12-01" @default.
• W2332164467 modified "2023-09-27" @default.
• W2332164467 title "ATTENUATED TOTAL-REFLECTION INFRARED MICROSPECTROSCOPY OF PARTIALLY DISORDERED ZIRCON" @default.
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• W2332164467 doi "https://doi.org/10.3749/canmin.48.5.1409" @default.
• W2332164467 hasPublicationYear "2010" @default.
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