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• W2332255504 abstract "The effect of dynamic arm exchange on the crystallization and the jamming of multiarm starlike polymers was studied using small angle x-ray scattering and rheology. Poly(ethylene oxide) end capped with a small hydrophobic chain formed spherical micelles in water. Dynamic arm exchange allowed rapid crystallization and caused a discontinuous liquid-solid transition in dense suspensions after cooling. It is shown here that this is caused by spontaneous fine-tuning of the number of arms per micelle (f). Elimination of arm exchange by in situ photo-cross-linking of the core did not influence the behavior when f was at the optimum value. However, suboptimal values of f inhibited crystallization and the liquid-solid transition." @default.
• W2332255504 created "2016-06-24" @default.
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• W2332255504 date "2013-01-11" @default.
• W2332255504 modified "2023-10-18" @default.
• W2332255504 title "Dynamic Arm Exchange Facilitates Crystallization and Jamming of Starlike Polymers by Spontaneous Fine-Tuning of the Number of Arms" @default.
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• W2332255504 doi "https://doi.org/10.1103/physrevlett.110.028302" @default.
• W2332255504 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23383945" @default.
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