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• W2332289907 abstract "The microscopic features of binary solvent systems formed by molecular solvents (methanol, ethanol, 2-methylpropan-2-ol, water, pyridine, acetonitrile, 1-propanol, 2-propanol, dimethylformamide) and the ionic liquid ([bmim]BF 4 ) as cosolvent were used to select mixed solvents with particular characteristics. Molecular-microscopic solvent parameters corresponding to these binary mixtures were utilised to study the kinetics of the nucleophilic substitution reaction between 2-chloro-3,5-dinitropyridine and aniline to investigate and compare the effects of the solvents on a model chemical reaction. For these mixtures, the solvation behaviour is dominated by both the dipolarity/polarisability and hydrogen bonding interactions of the media. In these solutions, the rate constants of the reaction decrease with the mole fraction of ionic liquid." @default.
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• W2332289907 date "2013-06-01" @default.
• W2332289907 modified "2023-10-01" @default.
• W2332289907 title "Systems Designed with an Ionic Liquid and Molecular Solvents to Investigate the Kinetics of an S_NAr Reaction" @default.
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• W2332289907 doi "https://doi.org/10.3184/146867813x13632857557572" @default.
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