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- W2332314368 abstract "Crystals of a potassium-rich variant of the mineral tinsleyite were obtained by hydrothermal synthesis in the system K 2 O–Al 2 O 3 –P 2 O 5 –H 2 O. The new phase is monoclinic, space group P 2 1 / n , a 9.4352(7), b 9.5254(10), c 9.4309(7) A, β 101.421(7)°, Z = 4. Its crystal structure was solved from single-crystal data collected at 193 K and refined to R = 0.0293, including positions of all hydrogen atoms. The crystal structure is built of units of four AlO 6 octahedra sharing edges and vertices. The octahedron units are cross-linked by PO 4 tetrahedra to form a three-dimensional framework with channels along the main crystallographic [010], [001] and [100] directions, where the large K + ions and H 2 O molecules are distributed. The system of O – H ... O asymmetric hydrogen bonds between H 2 O molecules, hydroxyl groups and framework oxygen atoms provides additional cross-linking in the structure. We show that a change in the alkalinity of the mineral-forming system correlates with the composition of the crystallizing phase and simultaneously influences the character of hydrogen bonding. The new K-rich variety of the tinsleyite is suggested as a possible mineral species. We evaluate the crystal chemistry of the leucophosphite group of minerals and the related synthetic compounds." @default.
- W2332314368 created "2016-06-24" @default.
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- W2332314368 date "2012-04-01" @default.
- W2332314368 modified "2023-09-23" @default.
- W2332314368 title "A NOVEL POTASSIUM-RICH VARIANT OF TINSLEYITE, K1.5(H2O)0.5 [Al2(OH) (PO4)2]" @default.
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- W2332314368 doi "https://doi.org/10.3749/canmin.50.2.559" @default.
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