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- W2332328275 abstract "Rate-based models suitable for equipment or transport-reaction modeling require a capability for predicting transport coefficients over a sufficient range of temperature and pressure. This paper demonstrates a relatively simple novel approach to correlate and estimate transport coefficients for pure components over the entire fluid region.The use of Chapman-Enskog transport coefficients for reducing self-diffusion coefficient and viscosity to dimensionless form results in relatively simple mathematical relationships between component dimensionless transport coefficients and residual entropy over the entire fluid region. Dimensionless self-diffusion coefficients and viscosities were calculated from extensive molecular dynamics simulation data and experimental data on argon, methane, ethylene, ethane, propane, and n-decane. These dimensionless transport coefficients were plotted against dimensionless residual entropy calculated from highly accurate reference equations of state.Based on experimental data, the new scaling model introduced here shows promise as: (1) an equation of state-based transport coefficient correlation over the entire fluid region (liquid, gas, and critical fluid), (2) a component transport coefficient correlation for testing transport data consistency, and (3) a component transport coefficient correlation for interpolation and extrapolation of self-diffusion coefficient and viscosity." @default.
- W2332328275 created "2016-06-24" @default.
- W2332328275 creator A5054641056 @default.
- W2332328275 date "2011-07-18" @default.
- W2332328275 modified "2023-09-26" @default.
- W2332328275 title "Self-Diffusion Coefficient and Viscosity in Fluids" @default.
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- W2332328275 doi "https://doi.org/10.1515/1542-6580.2640" @default.
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