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• W2332344845 endingPage "2017" @default.
• W2332344845 startingPage "2012" @default.
• W2332344845 abstract "Reactions of the ansa-heteroborabenzene divalent ytterbium amide [C5H5BCH2(CH3)2P→BC5H5]YbN(SiMe3)2 (1) with alkali-metal salts (KC5Me5, NaOiPr, NaOAr, LiNHAr, LiN(SiMe3)2, LiNEt2, and KCH2Ar) were studied. The reaction of 1 with KC5Me5 caused a ligand displacement of neutral borabenzene by KC5Me5 at the Yb ion to give a heterometallic Yb−K boratabenzene complex with a polymeric structure, while that with NaOiPr caused a ligand displacement of the anionic amido ligand at the Yb ion by an isopropoxyl ligand to give a heterometallic Yb−Na boratabenzene complex with a polymeric structure. When LiNEt2 or KCH2Ar was employed as the reagent, the [NEt2]− or [CH2Ar]− group underwent nucleophilic attack at the B atom on the neutral borabenzene to cause the disassociation of the P→B coordination bond and the generation of new boratabenzene ligands." @default.
• W2332344845 created "2016-06-24" @default.
• W2332344845 creator A5024074324 @default.
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• W2332344845 creator A5058747937 @default.
• W2332344845 creator A5058990274 @default.
• W2332344845 date "2011-03-16" @default.
• W2332344845 modified "2023-10-11" @default.
• W2332344845 title "Versatile Reactivities of <i>ansa</i>-Heteroborabenzene Divalent Ytterbium Amide toward Alkali-Metal Salts and the Generation of Heterometallic Ytterbium−Alkali-Metal Boratabenzene Complexes" @default.
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• W2332344845 doi "https://doi.org/10.1021/om200040z" @default.
• W2332344845 hasPublicationYear "2011" @default.
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