FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2332378578> ?p ?o ?g. }

• W2332378578 endingPage "1191" @default.
• W2332378578 startingPage "1181" @default.
• W2332378578 abstract "Two K([2.2.2]crypt) salts of lanthanide-doped semimetal clusters were prepared, both of which contain at the same time two types of ternary intermetalloid anions, [Ln@Sn7Bi7]4– and [Ln@Sn4Bi9]4–, in 0.70:0.30 (Ln = La) or 0.39:0.61 (Ln = Ce) ratios. The cluster shells represent nondeltahedral, fullerane-type arrangements of 14 or 13 main group metal atoms that embed the Ln3+ cations. The assignment of formal +III oxidation states for the Ln sites was confirmed by means of magnetic measurements that reveal a diamagnetic La(III) compound and a paramagnetic Ce(III) analogue. Whereas the cluster anions with a 14-atomic main-group metal cage represent the second examples in addition to a related Eu(II) cluster published just recently, the 13-atomic cages exhibit a yet unprecedented enneahedral topology. In contrast to the larger cages, which accord to the Zintl–Klemm–Busmann electron number–structure correlation, the smaller clusters require a more profound interpretation of the bonding situation. Quantum chemical investigations served to shed light on these unusual complexes and showed significant narrowing of the HOMO–LUMO gap upon incorporation of Ce3+ within the semimetal cages." @default.
• W2332378578 created "2016-06-24" @default.
• W2332378578 creator A5009236644 @default.
• W2332378578 creator A5011993421 @default.
• W2332378578 creator A5020738851 @default.
• W2332378578 creator A5031459453 @default.
• W2332378578 creator A5054066214 @default.
• W2332378578 creator A5064393421 @default.
• W2332378578 creator A5076273697 @default.
• W2332378578 creator A5085989217 @default.
• W2332378578 date "2012-01-03" @default.
• W2332378578 modified "2023-10-12" @default.
• W2332378578 title "Doped Semimetal Clusters: Ternary, Intermetalloid Anions [Ln@Sn₇Bi₇]^4– and [Ln@Sn₄Bi₉]^4– (Ln = La, Ce) with Adjustable Magnetic Properties" @default.
• W2332378578 cites W1650728208 @default.
• W2332378578 cites W1964179887 @default.
• W2332378578 cites W1965890865 @default.
• W2332378578 cites W1968656757 @default.
• W2332378578 cites W1975458269 @default.
• W2332378578 cites W1980718745 @default.
• W2332378578 cites W1981537324 @default.
• W2332378578 cites W1984044268 @default.
• W2332378578 cites W1986561074 @default.
• W2332378578 cites W1988091937 @default.
• W2332378578 cites W1992754316 @default.
• W2332378578 cites W1993671107 @default.
• W2332378578 cites W1995507794 @default.
• W2332378578 cites W2006634130 @default.
• W2332378578 cites W2007196579 @default.
• W2332378578 cites W2011404269 @default.
• W2332378578 cites W2015115007 @default.
• W2332378578 cites W2015596408 @default.
• W2332378578 cites W2016453913 @default.
• W2332378578 cites W2017801758 @default.
• W2332378578 cites W2021050313 @default.
• W2332378578 cites W2023356162 @default.
• W2332378578 cites W2026627407 @default.
• W2332378578 cites W2028299411 @default.
• W2332378578 cites W2030670815 @default.
• W2332378578 cites W2030687437 @default.
• W2332378578 cites W2038533471 @default.
• W2332378578 cites W2040134477 @default.
• W2332378578 cites W2043671443 @default.
• W2332378578 cites W2046604198 @default.
• W2332378578 cites W2049048912 @default.
• W2332378578 cites W2050443915 @default.
• W2332378578 cites W2051245001 @default.
• W2332378578 cites W2055563809 @default.
• W2332378578 cites W2062058582 @default.
• W2332378578 cites W2063609545 @default.
• W2332378578 cites W2064659751 @default.
• W2332378578 cites W2065294064 @default.
• W2332378578 cites W2065692039 @default.
• W2332378578 cites W2067650379 @default.
• W2332378578 cites W2072737386 @default.
• W2332378578 cites W2077490493 @default.
• W2332378578 cites W2079910926 @default.
• W2332378578 cites W2082432717 @default.
• W2332378578 cites W2085341294 @default.
• W2332378578 cites W2086626782 @default.
• W2332378578 cites W2086957099 @default.
• W2332378578 cites W2088965396 @default.
• W2332378578 cites W2089708541 @default.
• W2332378578 cites W2089709277 @default.
• W2332378578 cites W2093076921 @default.
• W2332378578 cites W2093622029 @default.
• W2332378578 cites W2093988081 @default.
• W2332378578 cites W2098560244 @default.
• W2332378578 cites W2100614602 @default.
• W2332378578 cites W2117125626 @default.
• W2332378578 cites W2117482876 @default.
• W2332378578 cites W2119547517 @default.
• W2332378578 cites W2125691026 @default.
• W2332378578 cites W2144717230 @default.
• W2332378578 cites W2147044568 @default.
• W2332378578 cites W2150098183 @default.
• W2332378578 cites W2156663663 @default.
• W2332378578 cites W2164666129 @default.
• W2332378578 cites W2165818049 @default.
• W2332378578 cites W2952748025 @default.
• W2332378578 cites W4211257231 @default.
• W2332378578 cites W4231848526 @default.
• W2332378578 cites W4232371453 @default.
• W2332378578 cites W4235955785 @default.
• W2332378578 cites W4236210902 @default.
• W2332378578 cites W4239006037 @default.
• W2332378578 cites W4245374428 @default.
• W2332378578 cites W4248546452 @default.
• W2332378578 cites W947635323 @default.
• W2332378578 cites W2014125629 @default.
• W2332378578 doi "https://doi.org/10.1021/ja209226b" @default.
• W2332378578 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22111958" @default.
• W2332378578 hasPublicationYear "2012" @default.
• W2332378578 type Work @default.
• W2332378578 sameAs 2332378578 @default.
• W2332378578 citedByCount "87" @default.
• W2332378578 countsByYear W23323785782012 @default.
• W2332378578 countsByYear W23323785782013 @default.
• W2332378578 countsByYear W23323785782014 @default.

• next