Matches in SemOpenAlex for { <https://semopenalex.org/work/W2332392724> ?p ?o ?g. }
- W2332392724 endingPage "348" @default.
- W2332392724 startingPage "340" @default.
- W2332392724 abstract "First-row transition metal-containing ionic liquids (ILs) were synthesized and used to catalyze the degradation of poly(ethylene terephthalate) (PET) in ethylene glycol (EG). One important feature of these IL catalysts is that they have good thermal stability, and most of them, especially [bmim]2[CoCl4] (bmim = 1-butyl-3-methyl-imidazolium) and [bmim]2[ZnCl4], exhibit higher catalytic activity, compared with traditional catalysts, conventional IL catalysts, and some functional ILs. For example, utilizing [bmim]2[CoCl4] as catalyst, the conversion of PET, selectivity of bis(hydroxyethyl) terephthalate (BHET), and mass fraction of BHET in products reach up to 100%, 81.1%, and 95.7%, respectively, under atmospheric pressure at 175 °C for only 1.5 h. Another important feature is that BHET can be easily separated from these IL catalysts and has high purity. Moreover, recycling results show that [bmim]2[CoCl4] worked efficiently after being used six times. These all show that [bmim]2[CoCl4] is an excellent IL catalyst for the glycolysis of PET. Finally, based on in situ IR spectra and experimental results, the possible mechanism of degradation with synthesized IL is proposed." @default.
- W2332392724 created "2016-06-24" @default.
- W2332392724 creator A5009340564 @default.
- W2332392724 creator A5025032312 @default.
- W2332392724 creator A5058443777 @default.
- W2332392724 creator A5086308625 @default.
- W2332392724 date "2015-01-22" @default.
- W2332392724 modified "2023-10-09" @default.
- W2332392724 title "First-Row Transition Metal-Containing Ionic Liquids as Highly Active Catalysts for the Glycolysis of Poly(ethylene terephthalate) (PET)" @default.
- W2332392724 cites W1600292521 @default.
- W2332392724 cites W1970795622 @default.
- W2332392724 cites W1978903529 @default.
- W2332392724 cites W1982479518 @default.
- W2332392724 cites W1993315264 @default.
- W2332392724 cites W1994438459 @default.
- W2332392724 cites W2000034022 @default.
- W2332392724 cites W2001556863 @default.
- W2332392724 cites W2002575634 @default.
- W2332392724 cites W2005307077 @default.
- W2332392724 cites W2009114377 @default.
- W2332392724 cites W2010152849 @default.
- W2332392724 cites W2019327801 @default.
- W2332392724 cites W2037719297 @default.
- W2332392724 cites W2038826299 @default.
- W2332392724 cites W2054597255 @default.
- W2332392724 cites W2056095748 @default.
- W2332392724 cites W2057773183 @default.
- W2332392724 cites W2060328185 @default.
- W2332392724 cites W2060701117 @default.
- W2332392724 cites W2078777211 @default.
- W2332392724 cites W2089897670 @default.
- W2332392724 cites W2090695689 @default.
- W2332392724 cites W2091373398 @default.
- W2332392724 cites W2136615766 @default.
- W2332392724 cites W2143665720 @default.
- W2332392724 cites W2161267604 @default.
- W2332392724 cites W2166519693 @default.
- W2332392724 cites W2327957326 @default.
- W2332392724 cites W2951137729 @default.
- W2332392724 doi "https://doi.org/10.1021/sc5007522" @default.
- W2332392724 hasPublicationYear "2015" @default.
- W2332392724 type Work @default.
- W2332392724 sameAs 2332392724 @default.
- W2332392724 citedByCount "132" @default.
- W2332392724 countsByYear W23323927242015 @default.
- W2332392724 countsByYear W23323927242016 @default.
- W2332392724 countsByYear W23323927242017 @default.
- W2332392724 countsByYear W23323927242018 @default.
- W2332392724 countsByYear W23323927242019 @default.
- W2332392724 countsByYear W23323927242020 @default.
- W2332392724 countsByYear W23323927242021 @default.
- W2332392724 countsByYear W23323927242022 @default.
- W2332392724 countsByYear W23323927242023 @default.
- W2332392724 crossrefType "journal-article" @default.
- W2332392724 hasAuthorship W2332392724A5009340564 @default.
- W2332392724 hasAuthorship W2332392724A5025032312 @default.
- W2332392724 hasAuthorship W2332392724A5058443777 @default.
- W2332392724 hasAuthorship W2332392724A5086308625 @default.
- W2332392724 hasConcept C106773901 @default.
- W2332392724 hasConcept C118792377 @default.
- W2332392724 hasConcept C154881586 @default.
- W2332392724 hasConcept C161790260 @default.
- W2332392724 hasConcept C178790620 @default.
- W2332392724 hasConcept C185592680 @default.
- W2332392724 hasConcept C188027245 @default.
- W2332392724 hasConcept C2777516009 @default.
- W2332392724 hasConcept C2778597550 @default.
- W2332392724 hasConcept C2779679103 @default.
- W2332392724 hasConcept C41008148 @default.
- W2332392724 hasConcept C544153396 @default.
- W2332392724 hasConcept C59061564 @default.
- W2332392724 hasConcept C76155785 @default.
- W2332392724 hasConceptScore W2332392724C106773901 @default.
- W2332392724 hasConceptScore W2332392724C118792377 @default.
- W2332392724 hasConceptScore W2332392724C154881586 @default.
- W2332392724 hasConceptScore W2332392724C161790260 @default.
- W2332392724 hasConceptScore W2332392724C178790620 @default.
- W2332392724 hasConceptScore W2332392724C185592680 @default.
- W2332392724 hasConceptScore W2332392724C188027245 @default.
- W2332392724 hasConceptScore W2332392724C2777516009 @default.
- W2332392724 hasConceptScore W2332392724C2778597550 @default.
- W2332392724 hasConceptScore W2332392724C2779679103 @default.
- W2332392724 hasConceptScore W2332392724C41008148 @default.
- W2332392724 hasConceptScore W2332392724C544153396 @default.
- W2332392724 hasConceptScore W2332392724C59061564 @default.
- W2332392724 hasConceptScore W2332392724C76155785 @default.
- W2332392724 hasFunder F4320321001 @default.
- W2332392724 hasFunder F4320321540 @default.
- W2332392724 hasFunder F4320322919 @default.
- W2332392724 hasFunder F4320324174 @default.
- W2332392724 hasIssue "2" @default.
- W2332392724 hasLocation W23323927241 @default.
- W2332392724 hasOpenAccess W2332392724 @default.
- W2332392724 hasPrimaryLocation W23323927241 @default.
- W2332392724 hasRelatedWork W2010713780 @default.
- W2332392724 hasRelatedWork W2336900503 @default.
- W2332392724 hasRelatedWork W2347183863 @default.
- W2332392724 hasRelatedWork W2348041599 @default.