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- W2332396989 abstract "Reaction of aryl- and benzylsulfanopyridinium amidates bearing a methyl group in position 6 with 2 equiv of diphenylketene afforded a spiro-fused ring system: azoniabenzo[de]fluorine. By use of an excess amount of ketene, a distinct reaction was observed via which a 1H-pyrrolo[3,2-b]pyridin-2(3H)-one derivative was furnished. The structure of the tetracyclic spiro-fused ring system was unambiguously confirmed by X-ray diffraction, and its formation was rationalized by DFT calculations." @default.
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- W2332396989 date "2014-12-05" @default.
- W2332396989 modified "2023-10-14" @default.
- W2332396989 title "Transformation of Zwitterionic Pyridine Derivatives to a Spiro-Fused Ring System: Azoniabenzo[<i>de</i>]fluorine. Synthesis and Mechanistic Rationalization" @default.
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- W2332396989 doi "https://doi.org/10.1021/jo5022663" @default.
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