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- W2332405632 abstract "A series of platinum phenyl olefin complexes has been prepared that bear hemilabile “Click”-triazole based scorpionate ligands (TtR). Mild heating of the olefin adducts initiates a reaction sequence to form stable, cationic Pt(IV) hydride metallacycles. An attractive mechanism involves κ3/κ2 conversion, phenyl migration, and ortho C–H activation. Activation parameters for the overall C–C bond-forming and C–H bond-breaking process were obtained. Insertion products from mono- and disubstituted olefins reveal a kinetic preference for phenyl migration to the less sterically hindered olefin position but a thermodynamic preference for the β-substituted metallacycle isomer, in which steric bulk is further away from the metal center and the TtR ligand. Thermolysis converts the kinetically favored products to their thermodynamically stable isomers via a reversible C–C bond cleavage and formation reaction. EXSY NMR and deuterium-labeling studies reveal facile scrambling processes in the metallacycles due to the hemilabile ligand." @default.
- W2332405632 created "2016-06-24" @default.
- W2332405632 creator A5018295014 @default.
- W2332405632 creator A5023371195 @default.
- W2332405632 date "2012-01-09" @default.
- W2332405632 modified "2023-10-16" @default.
- W2332405632 title "An Easy Conversion from Platinum(II) Reagents to Platinum(IV) Products: κ<sup>3</sup> to κ<sup>2</sup> Coordination Mode Interconversion, Phenyl Migration, and Ortho C–H Activation Cascade in a Hemilabile “Click”-Triazole Scorpionate Platinum System" @default.
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- W2332405632 doi "https://doi.org/10.1021/om2010595" @default.
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