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- W2332450521 abstract "The new oxyfluoride Pb 5 W 3 O 9 F 10 is found to crystallize in the tetragonal system with space group 14 and a=14.583, c=7.365 Å. The crystal structure is closely related to that of SrAlF 5 , previously shown to exhibit ferroelectric behavior. Generation of second harmonics in an atomic arrangement that readily allows reversal of the spontaneous polarization, a calculated Curie temperature of about 800 K, the experimental detection of a reversible phase transition at 785 K, a rapid rise in dielectric permittivity that reaches a maximum at the Curie temperature with a corresponding minimum in loss tangent, provide a set of sufficient and necessary conditions for ferroelectricity in Pb 5 W 3 O 9 F 10 ." @default.
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- W2332450521 date "1985-01-01" @default.
- W2332450521 modified "2023-09-25" @default.
- W2332450521 title "Ferroelectric Behavior and Phase Transition at 785 K in Pb<sub>5</sub>W<sub>3</sub>O<sub>9</sub>F<sub>10</sub>" @default.
- W2332450521 doi "https://doi.org/10.7567/jjaps.24s2.232" @default.
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