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- W2332457072 abstract "ヵチオン識別能をもった二分子膜の構築を目的として,親水基に15-クラウン-5および18-クラゥン-6 エーテル環をもち,ビフェニリレン基を含む一鎖疎水型両親媒性化合物1,2を合成した。18-クラウソ-6誘導体2は,カリウムイオン,特に酢酸カリウム存在下超音波照射によって水中に透明安定に分散した。カルボキシフルオレセィンを蛍光プローブとしてそのトラップ実験を行い,水を内包する粒子の存在を確認した。光散乱光度法で調べた粒径は,疎水基の大きさによってやや異なるものの,ゆ90～98w%以上が120～380Aの範囲にあった。mの分散によって生成したべシクルはイオン性化合物とは異なり,加熱によってベシクル構造は破壊され,内水相が放出された。脂肪酸塩あるいはアルキル硫酸塩を上記2の分散系に混合し,その影響を調べたところ,オレイン酸カリウムはじめカリウムィオンを対イオンとする界面活性物質の塩はi内包水をもった粒子からなる分散系をいちじるしく安定化すること,および小胞体の内包水の量に影響をおよぼすことが明らかとなった。" @default.
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- W2332457072 date "1990-01-01" @default.
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- W2332457072 title "Special articles on synthesis and supramolecular structure of functionality amphiphiles. Synthesis and vesicle-forming ability of the amphiphilic compound composed of a single lipophilic chain and a crown ether ring as a hydrophilic moiety." @default.
- W2332457072 doi "https://doi.org/10.1246/nikkashi.1990.1059" @default.
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