Matches in SemOpenAlex for { <https://semopenalex.org/work/W2332570285> ?p ?o ?g. }
- W2332570285 endingPage "153" @default.
- W2332570285 startingPage "150" @default.
- W2332570285 abstract "A palladium-catalyzed (3 + 2) cycloaddition of vinyl cyclopropane and α,β-unsaturated imines generated in situ from aryl sulfonyl indoles is reported. The reaction proceeds with high diastereoselectivity to provide the optically enriched spirocyclopentane-1,3'-indolenines in up to 74% yield and with up to 97% ee, which contains an all-carbon quaternary center and two tertiary stereocenters. The reaction involves a first conjugate addition of the carbon anion of zwitterionic π-allylpalladium complex from vinyl cyclopropane to the in situ formed unsaturated imine followed by a palladium-catalyzed intramolecular C3-allylation of indole." @default.
- W2332570285 created "2016-06-24" @default.
- W2332570285 creator A5017103019 @default.
- W2332570285 creator A5025116090 @default.
- W2332570285 creator A5049523725 @default.
- W2332570285 creator A5065177553 @default.
- W2332570285 creator A5065267589 @default.
- W2332570285 date "2014-12-19" @default.
- W2332570285 modified "2023-10-05" @default.
- W2332570285 title "Palladium-Catalyzed Asymmetric Cycloadditions of Vinylcyclopropanes and in Situ Formed Unsaturated Imines: Construction of Structurally and Optically Enriched Spiroindolenines" @default.
- W2332570285 cites W1967638553 @default.
- W2332570285 cites W1968870467 @default.
- W2332570285 cites W1979034929 @default.
- W2332570285 cites W1985848651 @default.
- W2332570285 cites W1987218271 @default.
- W2332570285 cites W1991702876 @default.
- W2332570285 cites W1996342244 @default.
- W2332570285 cites W2000630300 @default.
- W2332570285 cites W2001190014 @default.
- W2332570285 cites W2002988876 @default.
- W2332570285 cites W2006652076 @default.
- W2332570285 cites W2018198848 @default.
- W2332570285 cites W2038567620 @default.
- W2332570285 cites W2038645903 @default.
- W2332570285 cites W2046999219 @default.
- W2332570285 cites W2052315138 @default.
- W2332570285 cites W2055564123 @default.
- W2332570285 cites W2057437881 @default.
- W2332570285 cites W2059161628 @default.
- W2332570285 cites W2060413393 @default.
- W2332570285 cites W2061250139 @default.
- W2332570285 cites W2062720532 @default.
- W2332570285 cites W2067973899 @default.
- W2332570285 cites W2072809828 @default.
- W2332570285 cites W2073889294 @default.
- W2332570285 cites W2080606912 @default.
- W2332570285 cites W2083022810 @default.
- W2332570285 cites W2087197572 @default.
- W2332570285 cites W2092224765 @default.
- W2332570285 cites W2093310723 @default.
- W2332570285 cites W2109531150 @default.
- W2332570285 cites W2116665648 @default.
- W2332570285 cites W2116933801 @default.
- W2332570285 cites W2127983836 @default.
- W2332570285 cites W2131410272 @default.
- W2332570285 cites W2131765906 @default.
- W2332570285 cites W2131955149 @default.
- W2332570285 cites W2134690423 @default.
- W2332570285 cites W2146416398 @default.
- W2332570285 cites W2150112508 @default.
- W2332570285 cites W2156913324 @default.
- W2332570285 cites W2164566397 @default.
- W2332570285 cites W2168483177 @default.
- W2332570285 cites W2171579847 @default.
- W2332570285 cites W2312614484 @default.
- W2332570285 cites W2314827084 @default.
- W2332570285 cites W2315519216 @default.
- W2332570285 cites W2315766974 @default.
- W2332570285 cites W2316220332 @default.
- W2332570285 cites W2317770279 @default.
- W2332570285 cites W2321853215 @default.
- W2332570285 cites W2322422314 @default.
- W2332570285 cites W2322855977 @default.
- W2332570285 cites W2330414675 @default.
- W2332570285 cites W2331458772 @default.
- W2332570285 cites W4231486227 @default.
- W2332570285 cites W4243185557 @default.
- W2332570285 cites W4252779518 @default.
- W2332570285 cites W4256522147 @default.
- W2332570285 cites W4361865377 @default.
- W2332570285 cites W4380051093 @default.
- W2332570285 doi "https://doi.org/10.1021/ol503383x" @default.
- W2332570285 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25525709" @default.
- W2332570285 hasPublicationYear "2014" @default.
- W2332570285 type Work @default.
- W2332570285 sameAs 2332570285 @default.
- W2332570285 citedByCount "90" @default.
- W2332570285 countsByYear W23325702852015 @default.
- W2332570285 countsByYear W23325702852016 @default.
- W2332570285 countsByYear W23325702852017 @default.
- W2332570285 countsByYear W23325702852018 @default.
- W2332570285 countsByYear W23325702852019 @default.
- W2332570285 countsByYear W23325702852020 @default.
- W2332570285 countsByYear W23325702852021 @default.
- W2332570285 countsByYear W23325702852022 @default.
- W2332570285 countsByYear W23325702852023 @default.
- W2332570285 crossrefType "journal-article" @default.
- W2332570285 hasAuthorship W2332570285A5017103019 @default.
- W2332570285 hasAuthorship W2332570285A5025116090 @default.
- W2332570285 hasAuthorship W2332570285A5049523725 @default.
- W2332570285 hasAuthorship W2332570285A5065177553 @default.
- W2332570285 hasAuthorship W2332570285A5065267589 @default.
- W2332570285 hasConcept C134195300 @default.
- W2332570285 hasConcept C146686406 @default.
- W2332570285 hasConcept C155647269 @default.
- W2332570285 hasConcept C161790260 @default.
- W2332570285 hasConcept C178790620 @default.
- W2332570285 hasConcept C185592680 @default.