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- W2332664635 abstract "The additivity principle and solute-stationary phase interactions have been investigated for a series of mono-substituted alkylpyridines chromatographed on both polar and non-polar stationary phases. The increase in retention index due to electronic and steric effects arising from the position of the substituted alkyl group is discussed. It is concluded that the dominant factor controlling the chromatographic behaviour is the ring nitrogen atom and that a complex interrelationship between electronic and steric effects results in a non-linear increase in retention index on both stationary phases for a side-chain length of up to at least three carbon atoms." @default.
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- W2332664635 date "1974-05-01" @default.
- W2332664635 modified "2023-09-25" @default.
- W2332664635 title "Studies in the relationship between molecular structure and chromatographic behaviour" @default.
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- W2332664635 doi "https://doi.org/10.1016/s0021-9673(00)85738-6" @default.
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