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• W2332856646 endingPage "4198" @default.
• W2332856646 startingPage "4183" @default.
• W2332856646 abstract "The coordination of two heterofunctional P,P,S ligands of the N-functionalized DPPA-type bearing an alkylthioether or arylthioether N-substituent, (Ph2P)2N(CH2)3SMe (1) and (Ph2P)2N(p-C6H4)SMe (2), respectively, toward cobalt dichloride was investigated to examine the influence of the linker between the PNP nitrogen and the S atoms. The complexes [CoCl2(1)]2 (3) and [CoCl2(2)]2 (4) have been isolated, and 3 was shown by X-ray diffraction to be a unique dinuclear, zwitterion containing one CoCl moiety bis-chelated by two ligands 1 and one CoCl3 fragment coordinated by the S atom of a thioether function. The FT-IR, UV-vis, and EPR spectroscopic features of 3 were analyzed as the superposition of those of constitutive fragments identified by a retrosynthetic-type analysis. A similar approach provided insight into the nature of 4 for which no X-ray diffraction data could be obtained. A comparison between the spectroscopic features of 4 and of its constitutive fragments, [CoCl(2)2]PF6 (7) and [H2']2[CoCl4] (8) (2' = NH2(p-C6H4)SMe), and between those of 4 and 3 suggested that 4 could either have a zwitterionic structure, similar to that of 3, or contain a tetrahedral dicationic bis-chelated Co center associated with a CoCl4 dianion. Magnetic and EPR studies and theoretical calculations were performed. Doublet spin states were found for the pentacoordinated complexes [CoCl(1)2]PF6 (5) and 7 and anisotropic quadruplet spin states for the tetrahedral complexes [CoCl3(H1')] (6) (1' = NH2(CH2)3SMe) and 8. A very similar behavior was observed for 3 and 4, consisting in the juxtaposition of noninteracting doublet and quadruplet spin states. Antiferromagnetic interactions explain the formation of dimers for 6 and of layers for 8. The EPR signatures of 3 and 4 correspond to the superposition of low-spin nuclei in 5 and 7 and high-spin nuclei in 6 and 8, respectively. From DFT calculations, the solid-state structure of 4 appears best described as zwitterionic, with a low-spin state for the Co1 atom." @default.
• W2332856646 created "2016-06-24" @default.
• W2332856646 creator A5031864865 @default.
• W2332856646 creator A5032218532 @default.
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• W2332856646 creator A5051253782 @default.
• W2332856646 creator A5052167943 @default.
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• W2332856646 creator A5063605867 @default.
• W2332856646 creator A5084817853 @default.
• W2332856646 creator A5089677613 @default.
• W2332856646 date "2016-04-07" @default.
• W2332856646 modified "2023-10-10" @default.
• W2332856646 title "Zwitterionic Cobalt Complexes with Bis(diphenylphosphino)(<i>N</i>-thioether)amine Assembling Ligands: Structural, EPR, Magnetic, and Computational Studies" @default.
• W2332856646 cites W122392212 @default.
• W2332856646 cites W1520880984 @default.
• W2332856646 cites W1892980634 @default.
• W2332856646 cites W1965853743 @default.
• W2332856646 cites W1967189195 @default.
• W2332856646 cites W1967912156 @default.
• W2332856646 cites W1968199859 @default.
• W2332856646 cites W1968751790 @default.
• W2332856646 cites W1969000818 @default.
• W2332856646 cites W1970012666 @default.
• W2332856646 cites W1970033176 @default.
• W2332856646 cites W1970724497 @default.
• W2332856646 cites W1972210880 @default.
• W2332856646 cites W1972400761 @default.
• W2332856646 cites W1973196697 @default.
• W2332856646 cites W1974672258 @default.
• W2332856646 cites W1975338402 @default.
• W2332856646 cites W1977502962 @default.
• W2332856646 cites W1980079008 @default.
• W2332856646 cites W1984778587 @default.
• W2332856646 cites W1985470753 @default.
• W2332856646 cites W1989098365 @default.
• W2332856646 cites W1989649008 @default.
• W2332856646 cites W1990281198 @default.
• W2332856646 cites W1990643101 @default.
• W2332856646 cites W1991135369 @default.
• W2332856646 cites W1999710131 @default.
• W2332856646 cites W2000395961 @default.
• W2332856646 cites W2001235180 @default.
• W2332856646 cites W2005252491 @default.
• W2332856646 cites W2008870943 @default.
• W2332856646 cites W2012500601 @default.
• W2332856646 cites W2013649309 @default.
• W2332856646 cites W2013807059 @default.
• W2332856646 cites W2014749668 @default.
• W2332856646 cites W2016590095 @default.
• W2332856646 cites W2020630776 @default.
• W2332856646 cites W2023271753 @default.
• W2332856646 cites W2023612975 @default.
• W2332856646 cites W2023938769 @default.
• W2332856646 cites W2024367459 @default.
• W2332856646 cites W2025808437 @default.
• W2332856646 cites W2034142003 @default.
• W2332856646 cites W2036475784 @default.
• W2332856646 cites W2036775786 @default.
• W2332856646 cites W2038468763 @default.
• W2332856646 cites W2039565302 @default.
• W2332856646 cites W2042129035 @default.
• W2332856646 cites W2042819121 @default.
• W2332856646 cites W2052882513 @default.
• W2332856646 cites W2054150675 @default.
• W2332856646 cites W2054155704 @default.
• W2332856646 cites W2056408067 @default.
• W2332856646 cites W2058210956 @default.
• W2332856646 cites W2058877933 @default.
• W2332856646 cites W2059736644 @default.
• W2332856646 cites W2060968988 @default.
• W2332856646 cites W2061041297 @default.
• W2332856646 cites W2065378020 @default.
• W2332856646 cites W2065707019 @default.
• W2332856646 cites W2070733855 @default.
• W2332856646 cites W2070810336 @default.
• W2332856646 cites W2078146328 @default.
• W2332856646 cites W2080555698 @default.
• W2332856646 cites W2082993219 @default.
• W2332856646 cites W2083713331 @default.
• W2332856646 cites W2084176709 @default.
• W2332856646 cites W2084343499 @default.
• W2332856646 cites W2086827487 @default.
• W2332856646 cites W2112517381 @default.
• W2332856646 cites W2116644514 @default.
• W2332856646 cites W2122325094 @default.
• W2332856646 cites W2129972703 @default.
• W2332856646 cites W2131350133 @default.
• W2332856646 cites W2139419178 @default.
• W2332856646 cites W2140439409 @default.
• W2332856646 cites W2142395508 @default.
• W2332856646 cites W2143981217 @default.
• W2332856646 cites W2144332006 @default.
• W2332856646 cites W2166689829 @default.
• W2332856646 cites W2166976150 @default.
• W2332856646 cites W2300135740 @default.
• W2332856646 cites W2302129410 @default.
• W2332856646 cites W2314166474 @default.

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