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- W2332873537 abstract "Rare-earth compounds based on the stoichiometry R5(SixGe1−x)4 (R = rare-earth elements) exhibit many unusual features, including possessing R5(SixGe1−x)3 thin plates which always precipitate from the matrix despite efforts to suppress their formation. In an effort to better understand the unique relationship between these two intermetallic alloy systems, the bulk microstructure of the compound Gd5Ge3 was examined using scanning (SEM) and transmission electron microscopy (TEM) and optical microscopy. Surprisingly, SEM examination revealed a series of thin plates present in the Gd5Ge3 matrix similar to what is seen in Gd5Ge4. TEM observation revealed that a role reversal had occurred, with the thin plates possessing the orthorhombic structure and composition of Gd5Ge4. The orientation relationship between Gd5Ge4 thin plates and the Gd5Ge3 matrix was determined to be the same relationship reported for Gd5Ge3 plates precipitating from a Gd5Ge4 matrix. However, by exchanging the respective roles of the phases as regards matrix vs. precipitate, the total number of precipitation variants seen can be increased from two to six. The persistence with which these two intermetallic systems co-exist is truly unique. However, understanding exactly the kinetic and thermodynamic conditions that lead to their unique relationship is hampered by the high formation temperatures at which the observed reaction occurs." @default.
- W2332873537 created "2016-06-24" @default.
- W2332873537 creator A5043049997 @default.
- W2332873537 creator A5073472565 @default.
- W2332873537 date "2013-05-16" @default.
- W2332873537 modified "2023-09-25" @default.
- W2332873537 title "Characterization of second-phase plates in a Gd5Ge3intermetallic compound" @default.
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- W2332873537 doi "https://doi.org/10.1093/jmicro/dft029" @default.
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