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• W2332912225 abstract "Abstract The electrical conductances of the solutions of four tetraalkylammonium bromide salts (R 4 NBr), namely tetraethylammonium bromide (Et 4 NBr), tetrapropylammonium bromide (Pr 4 NBr), tetrapentylammonium bromide (Pen 4 NBr) and tetraheptylammonium bromide (Hep 4 NBr) in 2-ethoxyethanol have been reported at 35, 40, 45 and 50 °C. The conductance data have been analyzed by the 1978 Fuoss conductance–concentration equation in terms of the limiting molar conductance (Λ 0 ), the association constant ( K A ) and the association diameter ( R ). The ionic contributions to the limiting molar conductance have also been estimated. Appreciable ionic association was observed for all of these electrolytes in 2-ethoxyethanol. The tetraalkylammonium ions (R 4 N + ) were found to remain scarcely solvated in the present solvent medium within the temperature range investigated here. The solvation of the bromide ion in these tetraalkylammonium bromide is found to be weakened as soon as the ion-pairs are formed. An increase in the temperature results in a lower level of ion-pairing for each of these salts." @default.
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• W2332912225 date "2004-09-01" @default.
• W2332912225 modified "2023-10-18" @default.
• W2332912225 title "Conductometric Study of Some Tetraalkylammonium Bromides in 2-Ethoxyethanol in the Temperature Range 35–50 °C" @default.
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• W2332912225 doi "https://doi.org/10.1524/zpch.218.9.1129.41673" @default.
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