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- W2332980486 abstract "The new, unsymmetrical azobenzene-tagged ligand 4-(4-azobenzene)-3,6-di(2-pyridyl)pyridazine, adpp, forms complexes with platinum(II) and platinum(IV), which exist as a mixture of geometrical isomers. The complexes are characterized primarily by their NMR spectra, while the structures of the ligand and its complexes [PtMe 2 (adpp)], [PtBrMe 2 (CH 2 C 6 H 4 -4-t-Bu)(adpp)], and [PtBrMe 2 (CH 2 C 6 H 3 -3,5-t-Bu 2 )(adpp)] have been structurally characterized. In solution, the compounds undergo easy photochemical trans−cis switching of the azobenzene group, with subsequent slow thermal isomerization back to the more stable trans-azobenzene isomer." @default.
- W2332980486 created "2016-06-24" @default.
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- W2332980486 date "2014-08-01" @default.
- W2332980486 modified "2023-09-25" @default.
- W2332980486 title "Photoswitchable organoplatinum complexes containing an azobenzene derivative of 3,6-di(2-pyridyl)pyridazine" @default.
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- W2332980486 doi "https://doi.org/10.1139/cjc-2013-0588" @default.
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