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• W2333019471 abstract "We studied the thermal conductivity of various transition-metal oxides with the spinel structure $({mathrm{MnV}}_{2}{mathrm{O}}_{4}$, ${mathrm{FeV}}_{2}{mathrm{O}}_{4}$, ${mathrm{CoV}}_{2}{mathrm{O}}_{4}$, and ${mathrm{Mn}}_{3}{mathrm{O}}_{4})$ upon varying the temperature and magnetic field. We found that for the spinel oxides having ${mathrm{V}}^{3+}$ ions (two electrons in the ${t}_{2g}$ states) at the octahedral site, the orbital ordering suppresses the thermal resistivity (inverse thermal conductivity) in contrast to purely magnetic ordering, indicating that the orbital fluctuation of the V ${t}_{2g}$ states is the main factor affecting the thermal conductivity. On the other hand, for ${mathrm{Mn}}_{3}{mathrm{O}}_{4}$, which has ${mathrm{Mn}}^{3+}$ ions (one electron in the ${e}_{g}$ states) at the octahedral site, the thermal resistivity is suppressed in association with the successive magnetic phase transitions with decreasing temperature and increasing magnetic field. This can be explained by the frustration of ${mathrm{Mn}}^{3+}$ spins and the fluctuation of ${mathrm{Mn}}^{3+}$ ${e}_{g}$ orbitals." @default.
• W2333019471 created "2016-06-24" @default.
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• W2333019471 date "2014-12-08" @default.
• W2333019471 modified "2023-10-11" @default.
• W2333019471 title "Comparative studies of the thermal conductivity of spinel oxides with orbital degrees of freedom" @default.
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• W2333019471 doi "https://doi.org/10.1103/physrevb.90.224411" @default.
• W2333019471 hasPublicationYear "2014" @default.
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