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• W233304079 abstract "We report a detailed spectroscopic study of the pressure-induced neutral-ionic phase transition of the mixed-stack charge-transfer crystal tetrathiafulvalene-chloranil. We show that the pressure induced phase transition is still first-order and involves the presence of an intermediate disordered phase, defined by the coexistence of two species of different ionicity. Further application of pressure gradually converts this phase into an homogeneous ferroelectric phase with a single ionicity. In addition, we detect strong pretransitional phenomena which anticipate the intermediate phase and are indicative of a precursor dynamic regime dominated by fluctuations." @default.
• W233304079 created "2016-06-24" @default.
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• W233304079 date "2007-08-21" @default.
• W233304079 modified "2023-10-02" @default.
• W233304079 title "Intermediate regime in pressure-induced neutral-ionic transition in tetrathiafulvalene-chloranil" @default.
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• W233304079 doi "https://doi.org/10.1103/physrevb.76.064114" @default.
• W233304079 hasPublicationYear "2007" @default.
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