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- W2333048673 abstract "Abstract A series of salts containing the weakly coordinating cations (WCC) 1-butyl-3-methylimidazolium ([Bmim] + ), 1-butyl-2,3-dimethylimidazolium ([Bdmim] + ), 1-dodecyl-3-methylimidazolium ([C 12 mim] + ), tetrabutylphosphonium ([PBu 4 ] + ), tributyltetradecylphosphonium ([P 4;4;4;14 ] + ), tetrabutylammonium ([NBu 4 ] + ), and 1,1,3,3-tetramethylguanidium ([TMG] + ) and fluorinated tetraarylborate anions of the type [B(Ar F ) 4 ] (Ar F =C 6 F 5 , C 6 H 3 -3,5-(CF 3 ) 2 ) were synthesized and characterized. The influence of cations and anions on the physical properties of the obtained compounds was examined. In case of the compound [TMG][B(C 6 F 5 ) 4 ] hydrogen-fluorine contacts between cation and anion are present in the solid state. Owing to H···F contacts between hydrogen peroxide and the fluorine substituents of the anion and the resulting activation of H 2 O 2 in solution, the compound [P 4;4;4;14 ][B(C 6 H 3 -3,5-(CF 3 ) 2 ) 4 ] is applicable as an efficient mediator for the oxidation of sulfides to sulfoxides" @default.
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- W2333048673 date "2014-12-01" @default.
- W2333048673 modified "2023-10-10" @default.
- W2333048673 title "Ion Pairs of Weakly Coordinating Cations and Anions: Synthesis and Application for Sulfide to Sulfoxide Oxidations" @default.
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- W2333048673 doi "https://doi.org/10.5560/znb.2014-4165" @default.
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