FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2333099363> ?p ?o ?g. }

• W2333099363 endingPage "6742" @default.
• W2333099363 startingPage "6731" @default.
• W2333099363 abstract "Self-assembly of the Ln(III) ions (Ln = Eu, Gd, Dy, Ho, Yb) into square [2 × 2] grid-like arrays has been readily effected using simple, symmetric ditopic ligands based on a carbohydrazone core. The metal ions are connected via single atom bridges (e.g., μ2-O(hydrazone), μ2-OH, μ2-OMe, μ2-1,1-N3(-), μ4-O), depending on reaction conditions. The Gd(III)4 examples exhibit intramolecular antiferromagnetic exchange (-J < 0.11 cm(-1)), and in one Dy(III)4 example, with a combination of μ2-1,1-N3(-), and μ4-O bridges linking adjacent metal ions, SMM behavior is observed. One thermally driven relaxation process is observed in the temperature range 10-25 K (τ0 = 6.5(1) × 10(-7) s, U(eff) = 110(1) K) in the presence of an 1800 Oe external field, employed to suppress a second quantum based relaxation process. The extended group of Ln(III) ions which submit to this controlled self-assembly, typical of the transition metal ions, indicates the general applicability of this approach to the lanthanides. This occurs despite the anticipated limitations based on larger ionic radii and coordination numbers, and is an encouraging sign for extension to larger grids with appropriately chosen polytopic ligands." @default.
• W2333099363 created "2016-06-24" @default.
• W2333099363 creator A5004948560 @default.
• W2333099363 creator A5014243652 @default.
• W2333099363 creator A5036551021 @default.
• W2333099363 creator A5038961209 @default.
• W2333099363 creator A5054787606 @default.
• W2333099363 date "2013-05-16" @default.
• W2333099363 modified "2023-10-16" @default.
• W2333099363 title "Self-Assembled Ln(III)₄ (Ln = Eu, Gd, Dy, Ho, Yb) [2 × 2] Square Grids: a New Class of Lanthanide Cluster" @default.
• W2333099363 cites W1823409394 @default.
• W2333099363 cites W2008553568 @default.
• W2333099363 cites W2010241639 @default.
• W2333099363 cites W2010602654 @default.
• W2333099363 cites W2018473914 @default.
• W2333099363 cites W2037010322 @default.
• W2333099363 cites W2051935994 @default.
• W2333099363 cites W2053386380 @default.
• W2333099363 cites W2063857575 @default.
• W2333099363 cites W2066370105 @default.
• W2333099363 cites W2072172063 @default.
• W2333099363 cites W2082604185 @default.
• W2333099363 cites W2086096267 @default.
• W2333099363 cites W2089740902 @default.
• W2333099363 cites W2092308338 @default.
• W2333099363 cites W2103836230 @default.
• W2333099363 cites W2108975537 @default.
• W2333099363 cites W2109477907 @default.
• W2333099363 cites W2116195309 @default.
• W2333099363 cites W2131350133 @default.
• W2333099363 cites W2134324457 @default.
• W2333099363 cites W2144215650 @default.
• W2333099363 cites W2146099614 @default.
• W2333099363 cites W2157986221 @default.
• W2333099363 cites W2166052839 @default.
• W2333099363 cites W2166689829 @default.
• W2333099363 cites W2318964624 @default.
• W2333099363 cites W2331075809 @default.
• W2333099363 cites W4247932185 @default.
• W2333099363 cites W4253306097 @default.
• W2333099363 doi "https://doi.org/10.1021/ic4008813" @default.
• W2333099363 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23679218" @default.
• W2333099363 hasPublicationYear "2013" @default.
• W2333099363 type Work @default.
• W2333099363 sameAs 2333099363 @default.
• W2333099363 citedByCount "60" @default.
• W2333099363 countsByYear W23330993632014 @default.
• W2333099363 countsByYear W23330993632015 @default.
• W2333099363 countsByYear W23330993632016 @default.
• W2333099363 countsByYear W23330993632017 @default.
• W2333099363 countsByYear W23330993632018 @default.
• W2333099363 countsByYear W23330993632019 @default.
• W2333099363 countsByYear W23330993632020 @default.
• W2333099363 countsByYear W23330993632021 @default.
• W2333099363 countsByYear W23330993632022 @default.
• W2333099363 countsByYear W23330993632023 @default.
• W2333099363 crossrefType "journal-article" @default.
• W2333099363 hasAuthorship W2333099363A5004948560 @default.
• W2333099363 hasAuthorship W2333099363A5014243652 @default.
• W2333099363 hasAuthorship W2333099363A5036551021 @default.
• W2333099363 hasAuthorship W2333099363A5038961209 @default.
• W2333099363 hasAuthorship W2333099363A5054787606 @default.
• W2333099363 hasConcept C121332964 @default.
• W2333099363 hasConcept C145148216 @default.
• W2333099363 hasConcept C155355069 @default.
• W2333099363 hasConcept C164866538 @default.
• W2333099363 hasConcept C178790620 @default.
• W2333099363 hasConcept C185592680 @default.
• W2333099363 hasConcept C199164860 @default.
• W2333099363 hasConcept C199360897 @default.
• W2333099363 hasConcept C201770740 @default.
• W2333099363 hasConcept C26873012 @default.
• W2333099363 hasConcept C41008148 @default.
• W2333099363 hasConcept C544153396 @default.
• W2333099363 hasConcept C54998646 @default.
• W2333099363 hasConcept C71240020 @default.
• W2333099363 hasConcept C75079739 @default.
• W2333099363 hasConcept C8010536 @default.
• W2333099363 hasConceptScore W2333099363C121332964 @default.
• W2333099363 hasConceptScore W2333099363C145148216 @default.
• W2333099363 hasConceptScore W2333099363C155355069 @default.
• W2333099363 hasConceptScore W2333099363C164866538 @default.
• W2333099363 hasConceptScore W2333099363C178790620 @default.
• W2333099363 hasConceptScore W2333099363C185592680 @default.
• W2333099363 hasConceptScore W2333099363C199164860 @default.
• W2333099363 hasConceptScore W2333099363C199360897 @default.
• W2333099363 hasConceptScore W2333099363C201770740 @default.
• W2333099363 hasConceptScore W2333099363C26873012 @default.
• W2333099363 hasConceptScore W2333099363C41008148 @default.
• W2333099363 hasConceptScore W2333099363C544153396 @default.
• W2333099363 hasConceptScore W2333099363C54998646 @default.
• W2333099363 hasConceptScore W2333099363C71240020 @default.
• W2333099363 hasConceptScore W2333099363C75079739 @default.
• W2333099363 hasConceptScore W2333099363C8010536 @default.
• W2333099363 hasIssue "11" @default.
• W2333099363 hasLocation W23330993631 @default.
• W2333099363 hasLocation W23330993632 @default.
• W2333099363 hasOpenAccess W2333099363 @default.

• next