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• W2333246492 abstract "Reactions of tetraethyldilithiostannole 1 with [Cp*RuCl]4 afforded not η(5)-stannole dianion complexes but two novel bis(stannylene)-bridged dinuclear ruthenium complexes, which have butterfly and inverse-sandwich structures, respectively, depending on the stoichiometry of [Cp*RuCl]4 toward dilithiostannole. The redox behavior between the two complexes is found to be reversible. The molecular structures were determined by X-ray diffraction analysis. The Ru-Ru bond of the butterfly complex is 2.3428(6) Å, which is the shortest among those of dinuclear ruthenium complexes having Cp or Cp*Ru units. Theoretical calculations revealed that the very short Ru-Ru bond is due to the presence of one σ bond between the ruthenium atoms and two three-centered bonds delocalized over the two Ru2Sn rings." @default.
• W2333246492 created "2016-06-24" @default.
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• W2333246492 date "2013-03-18" @default.
• W2333246492 modified "2023-10-02" @default.
• W2333246492 title "Unexpected Formation of Ru₂Sn₂ Bicyclic Four-Membered Ring Complexes with Butterfly and Inverse-Sandwich Structures" @default.
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• W2333246492 doi "https://doi.org/10.1021/ic302782n" @default.
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