Matches in SemOpenAlex for { <https://semopenalex.org/work/W2333258192> ?p ?o ?g. }
- W2333258192 endingPage "2394" @default.
- W2333258192 startingPage "2387" @default.
- W2333258192 abstract "A long-standing question in olefin metathesis centers on whether the “release–return” (boomerang) mechanism contributes to the productivity of Hoveyda-class catalysts. According to this mechanism, a molecule of o-isopropoxystyrene (A) is liberated during catalyst initiation, but recaptures the active catalyst following metathesis. The relevance of this pathway for the second-generation Hoveyda catalyst HII was assessed in metathesis of 1,1- and 1,2-disubstituted olefins. Crossover studies with 13C-labeled A*, as well as competition experiments involving ring-closing or cross metathesis (RCM, CM) in the presence of A (equimolar with HII) indicated rapid reuptake of styrenyl ether. The crossover studies indicated highly efficient catalyst initiation, with the entire catalyst charge being activated before metathesis was complete. In a comparative study involving CM of anethole with methyl acrylate, sustained activity was shown for HII, whereas the second-generation Grubbs catalyst GII was rapidly deactivated..." @default.
- W2333258192 created "2016-06-24" @default.
- W2333258192 creator A5010060889 @default.
- W2333258192 creator A5021150865 @default.
- W2333258192 creator A5074755296 @default.
- W2333258192 creator A5077537923 @default.
- W2333258192 date "2014-06-24" @default.
- W2333258192 modified "2023-09-30" @default.
- W2333258192 title "Operation of the Boomerang Mechanism in Olefin Metathesis Reactions Promoted by the Second-Generation Hoveyda Catalyst" @default.
- W2333258192 cites W1496363913 @default.
- W2333258192 cites W1965748825 @default.
- W2333258192 cites W1965994123 @default.
- W2333258192 cites W1967668072 @default.
- W2333258192 cites W1971932112 @default.
- W2333258192 cites W1976440863 @default.
- W2333258192 cites W1976441157 @default.
- W2333258192 cites W1978903633 @default.
- W2333258192 cites W1982069969 @default.
- W2333258192 cites W1985108907 @default.
- W2333258192 cites W1986343191 @default.
- W2333258192 cites W1991959367 @default.
- W2333258192 cites W2000411331 @default.
- W2333258192 cites W2001338554 @default.
- W2333258192 cites W2004027588 @default.
- W2333258192 cites W2009441924 @default.
- W2333258192 cites W2015127086 @default.
- W2333258192 cites W2015998822 @default.
- W2333258192 cites W2016483322 @default.
- W2333258192 cites W2018050393 @default.
- W2333258192 cites W2022974342 @default.
- W2333258192 cites W2028888113 @default.
- W2333258192 cites W2028955188 @default.
- W2333258192 cites W2032487474 @default.
- W2333258192 cites W2034355791 @default.
- W2333258192 cites W2047456621 @default.
- W2333258192 cites W2048145471 @default.
- W2333258192 cites W2050774331 @default.
- W2333258192 cites W2064941851 @default.
- W2333258192 cites W2066657189 @default.
- W2333258192 cites W2068371599 @default.
- W2333258192 cites W2068580249 @default.
- W2333258192 cites W2071183734 @default.
- W2333258192 cites W2073365466 @default.
- W2333258192 cites W2074403861 @default.
- W2333258192 cites W2075603004 @default.
- W2333258192 cites W2080850843 @default.
- W2333258192 cites W2082299288 @default.
- W2333258192 cites W2091330739 @default.
- W2333258192 cites W2095481098 @default.
- W2333258192 cites W2096408932 @default.
- W2333258192 cites W2099799886 @default.
- W2333258192 cites W2104542134 @default.
- W2333258192 cites W2107386667 @default.
- W2333258192 cites W2112486821 @default.
- W2333258192 cites W2121030332 @default.
- W2333258192 cites W2121842366 @default.
- W2333258192 cites W2130850158 @default.
- W2333258192 cites W2141723905 @default.
- W2333258192 cites W2154445203 @default.
- W2333258192 cites W2168672157 @default.
- W2333258192 cites W2177093154 @default.
- W2333258192 cites W2315753115 @default.
- W2333258192 cites W2326196865 @default.
- W2333258192 cites W2335202970 @default.
- W2333258192 cites W2950746996 @default.
- W2333258192 cites W2951258726 @default.
- W2333258192 cites W2952179159 @default.
- W2333258192 cites W6021378 @default.
- W2333258192 doi "https://doi.org/10.1021/cs500539m" @default.
- W2333258192 hasPublicationYear "2014" @default.
- W2333258192 type Work @default.
- W2333258192 sameAs 2333258192 @default.
- W2333258192 citedByCount "77" @default.
- W2333258192 countsByYear W23332581922014 @default.
- W2333258192 countsByYear W23332581922015 @default.
- W2333258192 countsByYear W23332581922016 @default.
- W2333258192 countsByYear W23332581922017 @default.
- W2333258192 countsByYear W23332581922018 @default.
- W2333258192 countsByYear W23332581922019 @default.
- W2333258192 countsByYear W23332581922020 @default.
- W2333258192 countsByYear W23332581922021 @default.
- W2333258192 countsByYear W23332581922022 @default.
- W2333258192 countsByYear W23332581922023 @default.
- W2333258192 crossrefType "journal-article" @default.
- W2333258192 hasAuthorship W2333258192A5010060889 @default.
- W2333258192 hasAuthorship W2333258192A5021150865 @default.
- W2333258192 hasAuthorship W2333258192A5074755296 @default.
- W2333258192 hasAuthorship W2333258192A5077537923 @default.
- W2333258192 hasConcept C111472728 @default.
- W2333258192 hasConcept C138885662 @default.
- W2333258192 hasConcept C153914509 @default.
- W2333258192 hasConcept C161790260 @default.
- W2333258192 hasConcept C178790620 @default.
- W2333258192 hasConcept C185592680 @default.
- W2333258192 hasConcept C21951064 @default.
- W2333258192 hasConcept C2994504213 @default.
- W2333258192 hasConcept C44228677 @default.
- W2333258192 hasConcept C51886252 @default.