FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2333380147> ?p ?o ?g. }

• W2333380147 endingPage "8972" @default.
• W2333380147 startingPage "8964" @default.
• W2333380147 abstract "Amide and lithium aryloxide gallates [Li+{RGaPh3}−] (R = NMe2, O-2,6-Me2C6H3) react with the μ3-alkylidyne oxoderivative ligand [{Ti(η5-C5Me5)(μ-O)}3(μ3-CH)] (1) to afford the gallium–lithium–titanium cubane complexes [{Ph3Ga(μ-R)Li}{Ti(η5-C5Me5)(μ-O)}3(μ3-CH)] [R = NMe2 (3), O-2,6-Me2C6H3 (4)]. The same complexes can be obtained by treatment of the [Ph3Ga(μ3-O)3{Ti(η5-C5Me5)}3(μ3-CH)] (2) adduct with the corresponding lithium amide or aryloxide, respectively. Complex 3 evolves with formation of 5 as a solvent-separated ion pair constituted by the lithium dicubane cationic species [Li{(μ3-O)3Ti3(η5-C5Me5)3(μ3-CH)}2]+ together with the anionic [(GaPh3)2(μ-NMe2)]− unit. On the other hand, the reaction of 1 with Li(p-MeC6H4) and GaPh3 leads to the complex [Li{(μ3-O)3Ti3(η5-C5Me5)3(μ3-CH)}2][GaLi(p-MeC6H4)2Ph3] (6). X-ray diffraction studies were performed on 1, 2, 4, and 5, while trials to obtain crystals of 6 led to characterization of [Li{(μ3-O)3Ti3(η5-C5Me5)3(μ3-CH)}2][PhLi(μ-C6H5)2Ga(p-MeC6H4)Ph] 6a." @default.
• W2333380147 created "2016-06-24" @default.
• W2333380147 creator A5064413621 @default.
• W2333380147 creator A5074524641 @default.
• W2333380147 creator A5077228638 @default.
• W2333380147 creator A5080022184 @default.
• W2333380147 creator A5084218861 @default.
• W2333380147 creator A5085065303 @default.
• W2333380147 date "2012-07-30" @default.
• W2333380147 modified "2023-10-15" @default.
• W2333380147 title "Co-complexation of Lithium Gallates on the Titanium Molecular Oxide {[Ti(η⁵-C₅Me₅)(μ-O)}₃(μ₃-CH)]" @default.
• W2333380147 cites W1963644902 @default.
• W2333380147 cites W1966607459 @default.
• W2333380147 cites W1966624161 @default.
• W2333380147 cites W1967755754 @default.
• W2333380147 cites W1968770203 @default.
• W2333380147 cites W1973133118 @default.
• W2333380147 cites W1976091149 @default.
• W2333380147 cites W1977613306 @default.
• W2333380147 cites W1979295936 @default.
• W2333380147 cites W1979734220 @default.
• W2333380147 cites W1993581416 @default.
• W2333380147 cites W1993920497 @default.
• W2333380147 cites W1994787041 @default.
• W2333380147 cites W2000872427 @default.
• W2333380147 cites W2007751121 @default.
• W2333380147 cites W2012609329 @default.
• W2333380147 cites W2012776603 @default.
• W2333380147 cites W2014309678 @default.
• W2333380147 cites W2018200119 @default.
• W2333380147 cites W2024850422 @default.
• W2333380147 cites W2025128950 @default.
• W2333380147 cites W2025672631 @default.
• W2333380147 cites W2030635696 @default.
• W2333380147 cites W2031740863 @default.
• W2333380147 cites W2032566413 @default.
• W2333380147 cites W2033946942 @default.
• W2333380147 cites W2035582781 @default.
• W2333380147 cites W2041173826 @default.
• W2333380147 cites W2043767622 @default.
• W2333380147 cites W2048226783 @default.
• W2333380147 cites W2049691144 @default.
• W2333380147 cites W2051629274 @default.
• W2333380147 cites W2052967986 @default.
• W2333380147 cites W2054843936 @default.
• W2333380147 cites W2057446410 @default.
• W2333380147 cites W2060627363 @default.
• W2333380147 cites W2061904943 @default.
• W2333380147 cites W2063334178 @default.
• W2333380147 cites W2064054344 @default.
• W2333380147 cites W2064661036 @default.
• W2333380147 cites W2069438419 @default.
• W2333380147 cites W2074794518 @default.
• W2333380147 cites W2080706709 @default.
• W2333380147 cites W2081830806 @default.
• W2333380147 cites W2084654585 @default.
• W2333380147 cites W2085410297 @default.
• W2333380147 cites W2089496419 @default.
• W2333380147 cites W2089902034 @default.
• W2333380147 cites W2090224921 @default.
• W2333380147 cites W2093493344 @default.
• W2333380147 cites W2099928066 @default.
• W2333380147 cites W2115714343 @default.
• W2333380147 cites W2117038048 @default.
• W2333380147 cites W2119714412 @default.
• W2333380147 cites W2124761540 @default.
• W2333380147 cites W2131350133 @default.
• W2333380147 cites W2141424249 @default.
• W2333380147 cites W2153431172 @default.
• W2333380147 cites W2159328104 @default.
• W2333380147 cites W2162278543 @default.
• W2333380147 cites W2169379084 @default.
• W2333380147 cites W2322451544 @default.
• W2333380147 cites W2950002877 @default.
• W2333380147 cites W2953013629 @default.
• W2333380147 doi "https://doi.org/10.1021/ic301057u" @default.
• W2333380147 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22845551" @default.
• W2333380147 hasPublicationYear "2012" @default.
• W2333380147 type Work @default.
• W2333380147 sameAs 2333380147 @default.
• W2333380147 citedByCount "12" @default.
• W2333380147 countsByYear W23333801472013 @default.
• W2333380147 countsByYear W23333801472017 @default.
• W2333380147 countsByYear W23333801472018 @default.
• W2333380147 countsByYear W23333801472021 @default.
• W2333380147 countsByYear W23333801472023 @default.
• W2333380147 crossrefType "journal-article" @default.
• W2333380147 hasAuthorship W2333380147A5064413621 @default.
• W2333380147 hasAuthorship W2333380147A5074524641 @default.
• W2333380147 hasAuthorship W2333380147A5077228638 @default.
• W2333380147 hasAuthorship W2333380147A5080022184 @default.
• W2333380147 hasAuthorship W2333380147A5084218861 @default.
• W2333380147 hasAuthorship W2333380147A5085065303 @default.
• W2333380147 hasConcept C108204754 @default.
• W2333380147 hasConcept C116569031 @default.
• W2333380147 hasConcept C120665830 @default.
• W2333380147 hasConcept C121332964 @default.
• W2333380147 hasConcept C134018914 @default.

• next