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- W2333400475 abstract "Single-crystalline alkaline-earth metal manganites CaMn3O6, SrMn3O6–x and Ba6Mn24O48 nanoribbons have been successfully synthesized by a facile ion-exchange approach based on molten-salt reaction between Na0.44MnO2 nanoribbons and CaCl2, SrCl2, and BaCl2. All of these as-prepared nanoribbons are investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and high-resolution transmission electron microscopy (HRTEM). Taking the synthesis of single-crystalline SrMn3O6–x nanoribbons as an example, we researched in detail the conversion process from Na0.44MnO2 nanoribbons to SrMn3O6–x nanoribbons. Our results indicate that Na0.44MnO2 nanoribbons serve as the precursor template and the final products are obtained via ion-exchange reaction. Although there is a complete cation exchange, a change in stoichiometry, and a change in crystal structure, the morphology is nearly perfectly maintained. The synthetic method is thought to be a self-sacrificing templating route." @default.
- W2333400475 created "2016-06-24" @default.
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- W2333400475 date "2011-05-26" @default.
- W2333400475 modified "2023-09-27" @default.
- W2333400475 title "Synthesis of Single-Crystalline Alkaline-Earth Metal Manganites Nanoribbons via Cation Exchange" @default.
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- W2333400475 doi "https://doi.org/10.1021/cg101678d" @default.
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