Matches in SemOpenAlex for { <https://semopenalex.org/work/W2333487550> ?p ?o ?g. }
- W2333487550 endingPage "3896" @default.
- W2333487550 startingPage "3892" @default.
- W2333487550 abstract "The formation of an aryltellurenyl hydroxide analogue proposed in the telluroxide elimination reaction has been studied. The reaction of the monotelluride dimethyl 5-tert-butyl-2-(butyltellanyl)isophthalate (6) with H2O2 afforded the corresponding aryldiacyloxy-n-butyltellurane (8). The reaction of 6 with oxygen in the presence of moisture resulted in the formation of 8 as the major product along with traces of dimethyl 5-tert-butyl-2-(butyltellurinyl)isophthalate (7) and methyl 5-tert-butyl-3-oxo-3H-benzo[c][1,2]oxa tellurole-7-carboxylate (9). The telluroxide intermediate 7 readily undergoes a facile elimination reaction to give the elusive aryltellurenyl hydroxide, which is immediately trapped by the adjacent methyl ester functionality to give the cyclic tellurenate ester 9. Similarly, the hydrolysis of 7 with H2O affords the corresponding dihydroxytellurane 10, which is immediately converted to tellurane 8. Both compounds 8 and 9 have been characterized by single-crystal X-ray crystallographic studies." @default.
- W2333487550 created "2016-06-24" @default.
- W2333487550 creator A5015911823 @default.
- W2333487550 creator A5023343074 @default.
- W2333487550 creator A5062926793 @default.
- W2333487550 creator A5075883256 @default.
- W2333487550 date "2011-07-25" @default.
- W2333487550 modified "2023-09-26" @default.
- W2333487550 title "Methyl Ester Function: An Intramolecular Electrophilic Trap for the Isolation of Aryltellurenyl Hydroxide and Diorganotellurium Dihydroxide" @default.
- W2333487550 cites W1966468372 @default.
- W2333487550 cites W1971670666 @default.
- W2333487550 cites W1977535801 @default.
- W2333487550 cites W1981659539 @default.
- W2333487550 cites W1993419555 @default.
- W2333487550 cites W1994939815 @default.
- W2333487550 cites W2002887459 @default.
- W2333487550 cites W2004987775 @default.
- W2333487550 cites W2005061218 @default.
- W2333487550 cites W2006192357 @default.
- W2333487550 cites W2010928615 @default.
- W2333487550 cites W2013205478 @default.
- W2333487550 cites W2015396542 @default.
- W2333487550 cites W2015729471 @default.
- W2333487550 cites W2020167441 @default.
- W2333487550 cites W2026367648 @default.
- W2333487550 cites W2027054920 @default.
- W2333487550 cites W2034633789 @default.
- W2333487550 cites W2037318598 @default.
- W2333487550 cites W2039604352 @default.
- W2333487550 cites W2042186365 @default.
- W2333487550 cites W2047065711 @default.
- W2333487550 cites W2052638009 @default.
- W2333487550 cites W2059608925 @default.
- W2333487550 cites W2060430618 @default.
- W2333487550 cites W2063410457 @default.
- W2333487550 cites W2067114364 @default.
- W2333487550 cites W2067419184 @default.
- W2333487550 cites W2071016644 @default.
- W2333487550 cites W2077676461 @default.
- W2333487550 cites W2086584618 @default.
- W2333487550 cites W2092371218 @default.
- W2333487550 cites W2111938465 @default.
- W2333487550 cites W2115287419 @default.
- W2333487550 cites W2115433529 @default.
- W2333487550 cites W2120591546 @default.
- W2333487550 cites W2121237359 @default.
- W2333487550 cites W2141230543 @default.
- W2333487550 cites W2149216098 @default.
- W2333487550 cites W2312769075 @default.
- W2333487550 cites W2326712285 @default.
- W2333487550 cites W2953255880 @default.
- W2333487550 cites W3023077022 @default.
- W2333487550 cites W2084158548 @default.
- W2333487550 doi "https://doi.org/10.1021/om2001553" @default.
- W2333487550 hasPublicationYear "2011" @default.
- W2333487550 type Work @default.
- W2333487550 sameAs 2333487550 @default.
- W2333487550 citedByCount "11" @default.
- W2333487550 countsByYear W23334875502013 @default.
- W2333487550 countsByYear W23334875502016 @default.
- W2333487550 countsByYear W23334875502017 @default.
- W2333487550 countsByYear W23334875502018 @default.
- W2333487550 countsByYear W23334875502023 @default.
- W2333487550 crossrefType "journal-article" @default.
- W2333487550 hasAuthorship W2333487550A5015911823 @default.
- W2333487550 hasAuthorship W2333487550A5023343074 @default.
- W2333487550 hasAuthorship W2333487550A5062926793 @default.
- W2333487550 hasAuthorship W2333487550A5075883256 @default.
- W2333487550 hasConcept C155647269 @default.
- W2333487550 hasConcept C161790260 @default.
- W2333487550 hasConcept C178790620 @default.
- W2333487550 hasConcept C185592680 @default.
- W2333487550 hasConcept C2775896084 @default.
- W2333487550 hasConcept C2778074193 @default.
- W2333487550 hasConcept C50027330 @default.
- W2333487550 hasConcept C75079739 @default.
- W2333487550 hasConcept C94412978 @default.
- W2333487550 hasConceptScore W2333487550C155647269 @default.
- W2333487550 hasConceptScore W2333487550C161790260 @default.
- W2333487550 hasConceptScore W2333487550C178790620 @default.
- W2333487550 hasConceptScore W2333487550C185592680 @default.
- W2333487550 hasConceptScore W2333487550C2775896084 @default.
- W2333487550 hasConceptScore W2333487550C2778074193 @default.
- W2333487550 hasConceptScore W2333487550C50027330 @default.
- W2333487550 hasConceptScore W2333487550C75079739 @default.
- W2333487550 hasConceptScore W2333487550C94412978 @default.
- W2333487550 hasIssue "14" @default.
- W2333487550 hasLocation W23334875501 @default.
- W2333487550 hasOpenAccess W2333487550 @default.
- W2333487550 hasPrimaryLocation W23334875501 @default.
- W2333487550 hasRelatedWork W2023444917 @default.
- W2333487550 hasRelatedWork W2047923620 @default.
- W2333487550 hasRelatedWork W2060508868 @default.
- W2333487550 hasRelatedWork W2079032416 @default.
- W2333487550 hasRelatedWork W2316610396 @default.
- W2333487550 hasRelatedWork W2333487550 @default.
- W2333487550 hasRelatedWork W2949802101 @default.
- W2333487550 hasRelatedWork W2951757225 @default.