FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2333507101> ?p ?o ?g. }

• W2333507101 endingPage "19204" @default.
• W2333507101 startingPage "19198" @default.
• W2333507101 abstract "Dirhodium tetrakis-(R)-(1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylate) (Rh2(R-BTPCP)4) was found to be an effective chiral catalyst for enantioselective reactions of aryl- and styryldiazoacetates. Highly enantioselective cyclopropanations, tandem cyclopropanation/Cope rearrangements and a combined C–H functionalization/Cope rearrangement were achieved using Rh2(R-BTPCP)4 as catalyst. The advantages of Rh2(R-BTPCP)4 include its ease of synthesis, its tolerance to the size of the ester group in the styryldiazoacetates, and its compatibility with dichloromethane as solvent. Computational studies suggest that the catalyst adopts a D2-symmetric arrangement, but when the carbenoid binds to the catalyst, two of the p-bromophenyl groups on the ligands rotate outward to make room for the carbenoid and the approach of the substrate to the carbenoid." @default.
• W2333507101 created "2016-06-24" @default.
• W2333507101 creator A5012743614 @default.
• W2333507101 creator A5021165678 @default.
• W2333507101 creator A5028190786 @default.
• W2333507101 creator A5039007520 @default.
• W2333507101 creator A5052669292 @default.
• W2333507101 creator A5083948798 @default.
• W2333507101 date "2011-11-02" @default.
• W2333507101 modified "2023-09-26" @default.
• W2333507101 title "<i>D</i>₂-Symmetric Dirhodium Catalyst Derived from a 1,2,2-Triarylcyclopropanecarboxylate Ligand: Design, Synthesis and Application" @default.
• W2333507101 cites W1969457598 @default.
• W2333507101 cites W1971763054 @default.
• W2333507101 cites W1984232099 @default.
• W2333507101 cites W1989156004 @default.
• W2333507101 cites W1996177172 @default.
• W2333507101 cites W1996691257 @default.
• W2333507101 cites W1997173539 @default.
• W2333507101 cites W1999250336 @default.
• W2333507101 cites W2003774307 @default.
• W2333507101 cites W2009904876 @default.
• W2333507101 cites W2010192832 @default.
• W2333507101 cites W2013665598 @default.
• W2333507101 cites W2014809731 @default.
• W2333507101 cites W2017255626 @default.
• W2333507101 cites W2023271753 @default.
• W2333507101 cites W2023529053 @default.
• W2333507101 cites W2024874069 @default.
• W2333507101 cites W2027513085 @default.
• W2333507101 cites W2030971064 @default.
• W2333507101 cites W2033048991 @default.
• W2333507101 cites W2035228670 @default.
• W2333507101 cites W2043327592 @default.
• W2333507101 cites W2045151878 @default.
• W2333507101 cites W2047280630 @default.
• W2333507101 cites W2048455383 @default.
• W2333507101 cites W2051930185 @default.
• W2333507101 cites W2056594639 @default.
• W2333507101 cites W2073749587 @default.
• W2333507101 cites W2073813840 @default.
• W2333507101 cites W2080026836 @default.
• W2333507101 cites W2085403158 @default.
• W2333507101 cites W2088943937 @default.
• W2333507101 cites W2089634454 @default.
• W2333507101 cites W2094566251 @default.
• W2333507101 cites W2133975275 @default.
• W2333507101 cites W2143981217 @default.
• W2333507101 cites W2146776055 @default.
• W2333507101 cites W2147488303 @default.
• W2333507101 cites W2152862614 @default.
• W2333507101 cites W2161082904 @default.
• W2333507101 cites W2167199749 @default.
• W2333507101 cites W2318135678 @default.
• W2333507101 cites W2949983654 @default.
• W2333507101 cites W2950797181 @default.
• W2333507101 cites W2951260753 @default.
• W2333507101 cites W2952436361 @default.
• W2333507101 doi "https://doi.org/10.1021/ja2074104" @default.
• W2333507101 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22047062" @default.
• W2333507101 hasPublicationYear "2011" @default.
• W2333507101 type Work @default.
• W2333507101 sameAs 2333507101 @default.
• W2333507101 citedByCount "171" @default.
• W2333507101 countsByYear W23335071012012 @default.
• W2333507101 countsByYear W23335071012013 @default.
• W2333507101 countsByYear W23335071012014 @default.
• W2333507101 countsByYear W23335071012015 @default.
• W2333507101 countsByYear W23335071012016 @default.
• W2333507101 countsByYear W23335071012017 @default.
• W2333507101 countsByYear W23335071012018 @default.
• W2333507101 countsByYear W23335071012019 @default.
• W2333507101 countsByYear W23335071012020 @default.
• W2333507101 countsByYear W23335071012021 @default.
• W2333507101 countsByYear W23335071012022 @default.
• W2333507101 countsByYear W23335071012023 @default.
• W2333507101 crossrefType "journal-article" @default.
• W2333507101 hasAuthorship W2333507101A5012743614 @default.
• W2333507101 hasAuthorship W2333507101A5021165678 @default.
• W2333507101 hasAuthorship W2333507101A5028190786 @default.
• W2333507101 hasAuthorship W2333507101A5039007520 @default.
• W2333507101 hasAuthorship W2333507101A5052669292 @default.
• W2333507101 hasAuthorship W2333507101A5083948798 @default.
• W2333507101 hasConcept C116569031 @default.
• W2333507101 hasConcept C146686406 @default.
• W2333507101 hasConcept C155647269 @default.
• W2333507101 hasConcept C161790260 @default.
• W2333507101 hasConcept C170493617 @default.
• W2333507101 hasConcept C178790620 @default.
• W2333507101 hasConcept C185592680 @default.
• W2333507101 hasConcept C21951064 @default.
• W2333507101 hasConcept C2776920668 @default.
• W2333507101 hasConcept C2777052750 @default.
• W2333507101 hasConcept C2780263894 @default.
• W2333507101 hasConcept C2780400988 @default.
• W2333507101 hasConcept C2780471494 @default.
• W2333507101 hasConcept C2781076698 @default.
• W2333507101 hasConcept C521398313 @default.
• W2333507101 hasConcept C55493867 @default.

• next