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- W2333760219 abstract "In the present work, a combination of imaging, spectroscopic and computational methods shows that 1-dodecanethiol undergoes S-deprotonation to form 1-dodecanethiolate on the surface of palladium nanoparticles, which then self-assembles into a structure that shows a high degree of order. The alkyl chain is largely in the all-trans conformation, which occurs despite the small size of the nanoparticle, (mean diameter = 3.9 nm). Inelastic neutron scattering spectroscopy is readily able to characterise organic surface layers on nanoparticles; the nature of the material is irrelevant: whether the nanoparticle core is an oxide, a metal or a semiconductor makes no difference. Comparison to DFT calculations allows insights into the nature and conformation of the adsorbed layer." @default.
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- W2333760219 date "2016-01-01" @default.
- W2333760219 modified "2023-10-16" @default.
- W2333760219 title "The adsorbed state of a thiol on palladium nanoparticles" @default.
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- W2333760219 doi "https://doi.org/10.1039/c6cp00957c" @default.
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