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- W2333809139 abstract "The work described here represents the first example of an enantiopure hybrid scorpionate/cyclopentadiene ligand. The ligand was obtained in a one-pot synthetic procedure by an efficient and highly diastereoselective nucleophilic addition of an organolithium reagent to an electrophilically activated olefin in a new fulvene with a chiral substrate to control the stereochemistry of a newly created asymmetric center. We verified the potential utility of this ligand as a valuable scaffold that is able to induce chirality in organometallic/coordination chemistry. This was achieved through the preparation of a new enantiomerically pure zinc complex in which the ligand behaves in a tridentate manner with a κ2NN-η1(π)-Cp coordination mode. This alkylzinc complex constitutes the first example of an organozinc derivative which behaves as an efficient initiator for the ROP of rac-LA in the production of isotactic-enriched poly(lactides) with Pi = 0.77." @default.
- W2333809139 created "2016-06-24" @default.
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- W2333809139 date "2013-06-06" @default.
- W2333809139 modified "2023-10-14" @default.
- W2333809139 title "Efficient Synthesis of an Unprecedented Enantiopure Hybrid Scorpionate/Cyclopentadienyl by Diastereoselective Nucleophilic Addition to a Fulvene" @default.
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- W2333809139 doi "https://doi.org/10.1021/om4003279" @default.
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