FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2333820121> ?p ?o ?g. }

• W2333820121 endingPage "1204" @default.
• W2333820121 startingPage "1190" @default.
• W2333820121 abstract "The direct ortho arylation of 4-methyl-N-phenylpyridin-2-amines via palladium(II)-catalyzed C–H activation is described. Treatment of 4-methyl-N-phenylpyridin-2-amine with potassium aryltrifluoroborate using 10 mol % of palladium(II) acetate as the catalyst, 2 equiv of copper(II) acetate as the oxidant, and 1 equiv of p-benzoquinone in tert-butyl alcohol gave ortho-arylated products in modest to excellent yields. This reaction shows good functional group compatibility. A series of 1H NMR titration experiments and controlled experiments elucidating the reaction mechanism were carried out. The key intermediate, 4-methyl-N-phenylpyridin-2-amine palladacycle, was isolated and characterized by X-ray crystallography. The advanced transformations of ortho-phenylated 4-methyl-N-phenylpyridin-2-amine to N-(4-methylpyridin-2-yl)-9H-carbazole, biphenyl-2-amine, and 3-methyl-6-phenylpyrido[1,2-a]benzimidazole were successfully demonstrated as potential synthetic applications." @default.
• W2333820121 created "2016-06-24" @default.
• W2333820121 creator A5065455166 @default.
• W2333820121 creator A5067552759 @default.
• W2333820121 creator A5085711943 @default.
• W2333820121 creator A5014838004 @default.
• W2333820121 creator A5055505332 @default.
• W2333820121 date "2014-02-21" @default.
• W2333820121 modified "2023-10-09" @default.
• W2333820121 title "Palladium(II)-Catalyzed Direct Ortho Arylation of 4-Methyl-<i>N</i>-phenylpyridin-2-amines via C–H Activation/C–C Coupling and Synthetic Applications" @default.
• W2333820121 cites W1813465690 @default.
• W2333820121 cites W1975240837 @default.
• W2333820121 cites W1980099914 @default.
• W2333820121 cites W1982636233 @default.
• W2333820121 cites W1985353991 @default.
• W2333820121 cites W1989719625 @default.
• W2333820121 cites W1992593125 @default.
• W2333820121 cites W1999589112 @default.
• W2333820121 cites W2003509354 @default.
• W2333820121 cites W2010584571 @default.
• W2333820121 cites W2011088545 @default.
• W2333820121 cites W2018403322 @default.
• W2333820121 cites W2024044569 @default.
• W2333820121 cites W2033479134 @default.
• W2333820121 cites W2036044855 @default.
• W2333820121 cites W2044085614 @default.
• W2333820121 cites W2044903533 @default.
• W2333820121 cites W2048409876 @default.
• W2333820121 cites W2057086900 @default.
• W2333820121 cites W2058091693 @default.
• W2333820121 cites W2058792806 @default.
• W2333820121 cites W2060617807 @default.
• W2333820121 cites W2067433167 @default.
• W2333820121 cites W2068195780 @default.
• W2333820121 cites W2079115189 @default.
• W2333820121 cites W2088659286 @default.
• W2333820121 cites W2091324596 @default.
• W2333820121 cites W2095788658 @default.
• W2333820121 cites W2104742517 @default.
• W2333820121 cites W2109515899 @default.
• W2333820121 cites W2120208258 @default.
• W2333820121 cites W2124486126 @default.
• W2333820121 cites W2125014016 @default.
• W2333820121 cites W2128384293 @default.
• W2333820121 cites W2136886567 @default.
• W2333820121 cites W2140837933 @default.
• W2333820121 cites W2147599451 @default.
• W2333820121 cites W2150027462 @default.
• W2333820121 cites W2150338396 @default.
• W2333820121 cites W2155476546 @default.
• W2333820121 cites W2164023709 @default.
• W2333820121 cites W2167911022 @default.
• W2333820121 cites W2168812013 @default.
• W2333820121 cites W2170729971 @default.
• W2333820121 cites W2171921050 @default.
• W2333820121 cites W2316116473 @default.
• W2333820121 cites W2316389971 @default.
• W2333820121 cites W2324292327 @default.
• W2333820121 cites W2325906442 @default.
• W2333820121 cites W2329076747 @default.
• W2333820121 cites W2331452414 @default.
• W2333820121 cites W28714510 @default.
• W2333820121 cites W2950693595 @default.
• W2333820121 cites W2951176764 @default.
• W2333820121 cites W2951873816 @default.
• W2333820121 cites W2952778871 @default.
• W2333820121 doi "https://doi.org/10.1021/om401195w" @default.
• W2333820121 hasPublicationYear "2014" @default.
• W2333820121 type Work @default.
• W2333820121 sameAs 2333820121 @default.
• W2333820121 citedByCount "35" @default.
• W2333820121 countsByYear W23338201212014 @default.
• W2333820121 countsByYear W23338201212015 @default.
• W2333820121 countsByYear W23338201212016 @default.
• W2333820121 countsByYear W23338201212017 @default.
• W2333820121 countsByYear W23338201212018 @default.
• W2333820121 countsByYear W23338201212019 @default.
• W2333820121 countsByYear W23338201212020 @default.
• W2333820121 countsByYear W23338201212021 @default.
• W2333820121 countsByYear W23338201212022 @default.
• W2333820121 countsByYear W23338201212023 @default.
• W2333820121 crossrefType "journal-article" @default.
• W2333820121 hasAuthorship W2333820121A5014838004 @default.
• W2333820121 hasAuthorship W2333820121A5055505332 @default.
• W2333820121 hasAuthorship W2333820121A5065455166 @default.
• W2333820121 hasAuthorship W2333820121A5067552759 @default.
• W2333820121 hasAuthorship W2333820121A5085711943 @default.
• W2333820121 hasConcept C131779359 @default.
• W2333820121 hasConcept C155647269 @default.
• W2333820121 hasConcept C161790260 @default.
• W2333820121 hasConcept C178790620 @default.
• W2333820121 hasConcept C185592680 @default.
• W2333820121 hasConcept C198503264 @default.
• W2333820121 hasConcept C2776127813 @default.
• W2333820121 hasConcept C2776334562 @default.
• W2333820121 hasConcept C2778484023 @default.
• W2333820121 hasConcept C2780591471 @default.
• W2333820121 hasConcept C502130503 @default.

• next