FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2333972493> ?p ?o ?g. }

• W2333972493 endingPage "23581" @default.
• W2333972493 startingPage "23575" @default.
• W2333972493 abstract "The presence of approximately 10 mol % NaOH mixed with NaH powder is shown to result in much more rapid hydrogen motion in the NaH above 150 °C, as indicated by the onset of hydrogen NMR line narrowing at this temperature. A similar result appears for air-exposed NaH due to the formation of hydroxide from atmospheric H2O. The NMR line narrowing is too rapid, as a function of temperature, to be described by thermal activation; rather, it is suggestive of a phase transition. Indeed, differential scanning calorimetry finds, after an initial thermal cycle, a reversible thermal anomaly indicating a phase transition near 150 °C. Powder X-ray diffraction with an excess of NaOH displays a remarkable lattice expansion of the NaH in the temperature range of 100–240 °C where the (200), (220), and (311) reflections indicate a volume lattice expansion of up to 11%; the expansion is reversible upon cycling. The data thus point to a reversible phase transition in which NaOH enters the NaH structure above 150 °C and exits the NaH below that temperature. First-principles calculations using OH-substituted NaH supercells indicate significant solubility in the NaH lattice and find a transition temperature and enthalpy change that are in approximate agreement with differential scanning calorimetry (DSC) measurements, confirming the presence of a phase transition." @default.
• W2333972493 created "2016-06-24" @default.
• W2333972493 creator A5014154417 @default.
• W2333972493 creator A5017494688 @default.
• W2333972493 creator A5019797452 @default.
• W2333972493 creator A5034425988 @default.
• W2333972493 creator A5054628155 @default.
• W2333972493 creator A5064634018 @default.
• W2333972493 creator A5072827131 @default.
• W2333972493 creator A5080037660 @default.
• W2333972493 date "2013-11-01" @default.
• W2333972493 modified "2023-09-23" @default.
• W2333972493 title "Effects of NaOH in Solid NaH: Solution/Segregation Phase Transition and Diffusion Acceleration" @default.
• W2333972493 cites W1968376939 @default.
• W2333972493 cites W1970127494 @default.
• W2333972493 cites W1979544533 @default.
• W2333972493 cites W1982401237 @default.
• W2333972493 cites W1992592340 @default.
• W2333972493 cites W2016270720 @default.
• W2333972493 cites W2022447913 @default.
• W2333972493 cites W2031011743 @default.
• W2333972493 cites W2036113194 @default.
• W2333972493 cites W2044368194 @default.
• W2333972493 cites W2044601896 @default.
• W2333972493 cites W2056805753 @default.
• W2333972493 cites W2066860838 @default.
• W2333972493 cites W2071038343 @default.
• W2333972493 cites W2071900754 @default.
• W2333972493 cites W2079105963 @default.
• W2333972493 cites W2083222334 @default.
• W2333972493 cites W2094046471 @default.
• W2333972493 cites W2131197066 @default.
• W2333972493 cites W2146600796 @default.
• W2333972493 cites W2315470398 @default.
• W2333972493 cites W2321037150 @default.
• W2333972493 cites W2321726995 @default.
• W2333972493 cites W2322156744 @default.
• W2333972493 cites W2334404604 @default.
• W2333972493 cites W2952507794 @default.
• W2333972493 doi "https://doi.org/10.1021/jp4093892" @default.
• W2333972493 hasPublicationYear "2013" @default.
• W2333972493 type Work @default.
• W2333972493 sameAs 2333972493 @default.
• W2333972493 citedByCount "8" @default.
• W2333972493 countsByYear W23339724932014 @default.
• W2333972493 countsByYear W23339724932015 @default.
• W2333972493 countsByYear W23339724932016 @default.
• W2333972493 countsByYear W23339724932018 @default.
• W2333972493 countsByYear W23339724932020 @default.
• W2333972493 crossrefType "journal-article" @default.
• W2333972493 hasAuthorship W2333972493A5014154417 @default.
• W2333972493 hasAuthorship W2333972493A5017494688 @default.
• W2333972493 hasAuthorship W2333972493A5019797452 @default.
• W2333972493 hasAuthorship W2333972493A5034425988 @default.
• W2333972493 hasAuthorship W2333972493A5054628155 @default.
• W2333972493 hasAuthorship W2333972493A5064634018 @default.
• W2333972493 hasAuthorship W2333972493A5072827131 @default.
• W2333972493 hasAuthorship W2333972493A5080037660 @default.
• W2333972493 hasConcept C113196181 @default.
• W2333972493 hasConcept C121332964 @default.
• W2333972493 hasConcept C149288129 @default.
• W2333972493 hasConcept C178790620 @default.
• W2333972493 hasConcept C185592680 @default.
• W2333972493 hasConcept C191897082 @default.
• W2333972493 hasConcept C192562407 @default.
• W2333972493 hasConcept C202270520 @default.
• W2333972493 hasConcept C3288061 @default.
• W2333972493 hasConcept C39353612 @default.
• W2333972493 hasConcept C39519442 @default.
• W2333972493 hasConcept C47463417 @default.
• W2333972493 hasConcept C8010536 @default.
• W2333972493 hasConcept C97355855 @default.
• W2333972493 hasConceptScore W2333972493C113196181 @default.
• W2333972493 hasConceptScore W2333972493C121332964 @default.
• W2333972493 hasConceptScore W2333972493C149288129 @default.
• W2333972493 hasConceptScore W2333972493C178790620 @default.
• W2333972493 hasConceptScore W2333972493C185592680 @default.
• W2333972493 hasConceptScore W2333972493C191897082 @default.
• W2333972493 hasConceptScore W2333972493C192562407 @default.
• W2333972493 hasConceptScore W2333972493C202270520 @default.
• W2333972493 hasConceptScore W2333972493C3288061 @default.
• W2333972493 hasConceptScore W2333972493C39353612 @default.
• W2333972493 hasConceptScore W2333972493C39519442 @default.
• W2333972493 hasConceptScore W2333972493C47463417 @default.
• W2333972493 hasConceptScore W2333972493C8010536 @default.
• W2333972493 hasConceptScore W2333972493C97355855 @default.
• W2333972493 hasIssue "45" @default.
• W2333972493 hasLocation W23339724931 @default.
• W2333972493 hasOpenAccess W2333972493 @default.
• W2333972493 hasPrimaryLocation W23339724931 @default.
• W2333972493 hasRelatedWork W1970402587 @default.
• W2333972493 hasRelatedWork W1979618671 @default.
• W2333972493 hasRelatedWork W1988334684 @default.
• W2333972493 hasRelatedWork W1996591492 @default.
• W2333972493 hasRelatedWork W2034884025 @default.
• W2333972493 hasRelatedWork W2038766970 @default.
• W2333972493 hasRelatedWork W2052317294 @default.
• W2333972493 hasRelatedWork W2598109591 @default.

• next