Matches in SemOpenAlex for { <https://semopenalex.org/work/W2334002520> ?p ?o ?g. }
- W2334002520 endingPage "8277" @default.
- W2334002520 startingPage "8270" @default.
- W2334002520 abstract "The mononuclear diiodoplatinum(II) complex (trans-PtI2(cis-DHDAMe)2), where cis-DHDAMe = cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(methoxycarbonyl)-1,4-diarsinine, forms three different crystalline polymorphs that can be either concomitantly or separately obtained on varying the recrystallization conditions. Cubic red crystals (α-phase) and red-orange needles (β-phase) exhibit solid-state red emissions at room temperature. Cubic red crystals of the γ-phase show no solid-state emission at room temperature. All crystalline structures were confirmed by X-ray crystallography. Room-temperature strongly luminescent crystals (α-phase) (λem = 657 nm, Φ = 0.52) have a triclinic P1̅ (No. 2) structure and no voids in the crystal structure. Red-orange needle-shaped crystals of the β-phase exhibit moderate red luminescence (λem = 695 nm, Φ = 0.09) at room temperature and have a trigonal, R3̅ (No. 148), structure. In the needlelike crystals of the β-phase, stable hexagonal arrays of nanoporous channels, 5.0 Å in diameter, are formed. Room-temperature nonluminescent crystals (γ-phase) have an orthorhombic, Pbca (No. 61), structure with a void volume that is 4.9% of the total crystal volume. After heating the α-phase crystals at 150 °C for 2 min, a powder XRD pattern different from the original crystal is obtained, and its solid-state emission at room temperature decreased. After heating the β-phase crystals at 150 °C for 2 min, the emission wavelength and the quantum yield of the solid-state emission at room temperature and the powder XRD pattern are the same as those of the α-phase after heating at 150 °C. A crystal-to-crystal transition triggered by the thermal stimulus produces a different stable polymorph of the mononuclear diiodoplatinum(II) complex. The one-dimensional nanoporous crystals encapsulated iodine without distorting the crystal packing." @default.
- W2334002520 created "2016-06-24" @default.
- W2334002520 creator A5000301778 @default.
- W2334002520 creator A5024304082 @default.
- W2334002520 creator A5031959602 @default.
- W2334002520 creator A5052376362 @default.
- W2334002520 creator A5059082815 @default.
- W2334002520 date "2014-07-25" @default.
- W2334002520 modified "2023-09-30" @default.
- W2334002520 title "Polymorph Control of Luminescence Properties in Molecular Crystals of a Platinum and Organoarsenic Complex and Formation of Stable One-Dimensional Nanochannel" @default.
- W2334002520 cites W1976540925 @default.
- W2334002520 cites W1978416186 @default.
- W2334002520 cites W1993837608 @default.
- W2334002520 cites W1999051960 @default.
- W2334002520 cites W1999937609 @default.
- W2334002520 cites W2001515341 @default.
- W2334002520 cites W2002154139 @default.
- W2334002520 cites W2003111458 @default.
- W2334002520 cites W2007988193 @default.
- W2334002520 cites W2013564410 @default.
- W2334002520 cites W2014686266 @default.
- W2334002520 cites W2018032287 @default.
- W2334002520 cites W2046234505 @default.
- W2334002520 cites W2056418947 @default.
- W2334002520 cites W2057388892 @default.
- W2334002520 cites W2059457583 @default.
- W2334002520 cites W2062269633 @default.
- W2334002520 cites W2068138859 @default.
- W2334002520 cites W2069755098 @default.
- W2334002520 cites W2073695107 @default.
- W2334002520 cites W2084534953 @default.
- W2334002520 cites W2090504473 @default.
- W2334002520 cites W2091315145 @default.
- W2334002520 cites W2113763565 @default.
- W2334002520 cites W2314339184 @default.
- W2334002520 cites W2330947143 @default.
- W2334002520 doi "https://doi.org/10.1021/ic500550y" @default.
- W2334002520 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25061800" @default.
- W2334002520 hasPublicationYear "2014" @default.
- W2334002520 type Work @default.
- W2334002520 sameAs 2334002520 @default.
- W2334002520 citedByCount "25" @default.
- W2334002520 countsByYear W23340025202015 @default.
- W2334002520 countsByYear W23340025202016 @default.
- W2334002520 countsByYear W23340025202017 @default.
- W2334002520 countsByYear W23340025202018 @default.
- W2334002520 countsByYear W23340025202019 @default.
- W2334002520 countsByYear W23340025202020 @default.
- W2334002520 countsByYear W23340025202021 @default.
- W2334002520 countsByYear W23340025202022 @default.
- W2334002520 crossrefType "journal-article" @default.
- W2334002520 hasAuthorship W2334002520A5000301778 @default.
- W2334002520 hasAuthorship W2334002520A5024304082 @default.
- W2334002520 hasAuthorship W2334002520A5031959602 @default.
- W2334002520 hasAuthorship W2334002520A5052376362 @default.
- W2334002520 hasAuthorship W2334002520A5059082815 @default.
- W2334002520 hasConcept C113196181 @default.
- W2334002520 hasConcept C115624301 @default.
- W2334002520 hasConcept C120665830 @default.
- W2334002520 hasConcept C121332964 @default.
- W2334002520 hasConcept C128765274 @default.
- W2334002520 hasConcept C148869448 @default.
- W2334002520 hasConcept C178790620 @default.
- W2334002520 hasConcept C181817918 @default.
- W2334002520 hasConcept C185592680 @default.
- W2334002520 hasConcept C192562407 @default.
- W2334002520 hasConcept C199360897 @default.
- W2334002520 hasConcept C2780134926 @default.
- W2334002520 hasConcept C2781285689 @default.
- W2334002520 hasConcept C37243968 @default.
- W2334002520 hasConcept C41008148 @default.
- W2334002520 hasConcept C42228675 @default.
- W2334002520 hasConcept C44280652 @default.
- W2334002520 hasConcept C49040817 @default.
- W2334002520 hasConcept C8010536 @default.
- W2334002520 hasConcept C85080765 @default.
- W2334002520 hasConcept C91881484 @default.
- W2334002520 hasConceptScore W2334002520C113196181 @default.
- W2334002520 hasConceptScore W2334002520C115624301 @default.
- W2334002520 hasConceptScore W2334002520C120665830 @default.
- W2334002520 hasConceptScore W2334002520C121332964 @default.
- W2334002520 hasConceptScore W2334002520C128765274 @default.
- W2334002520 hasConceptScore W2334002520C148869448 @default.
- W2334002520 hasConceptScore W2334002520C178790620 @default.
- W2334002520 hasConceptScore W2334002520C181817918 @default.
- W2334002520 hasConceptScore W2334002520C185592680 @default.
- W2334002520 hasConceptScore W2334002520C192562407 @default.
- W2334002520 hasConceptScore W2334002520C199360897 @default.
- W2334002520 hasConceptScore W2334002520C2780134926 @default.
- W2334002520 hasConceptScore W2334002520C2781285689 @default.
- W2334002520 hasConceptScore W2334002520C37243968 @default.
- W2334002520 hasConceptScore W2334002520C41008148 @default.
- W2334002520 hasConceptScore W2334002520C42228675 @default.
- W2334002520 hasConceptScore W2334002520C44280652 @default.
- W2334002520 hasConceptScore W2334002520C49040817 @default.
- W2334002520 hasConceptScore W2334002520C8010536 @default.
- W2334002520 hasConceptScore W2334002520C85080765 @default.
- W2334002520 hasConceptScore W2334002520C91881484 @default.