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- W2334004853 abstract "Summary The FT-IR (Fourier transform infrared spectroscopy) spectrum of IO 3 − adsorbed in the interlayer of NO 3 − hydrotalcite (HTNO 3 ) was determined. The v 3 vibration modes of IO 3 − split into two peaks. All peaks caused by adsorbed IO 3 − were found to be shifted to the lower wavelength region relative to the peaks observed from IO 3 − in the KIO 3 crystal. This suggested that IO 3 − adsorbed in the interlayer of HTNO 3 has asymmetry different from the original C 3v symmetrical structure of aqueous IO 3 − . The structural position of IO 3 − in the interlayer of HTNO 3 was optimized using the CASTEP ( C ambridge s erial t otal e nergy p ackage) code. This code is based on density functional theory (DFT) calculations for crystal structures. It was found that the hydroxyl groups bound to O atoms of IO 3 − are not uniform. This may lead to the structural change of adsorbed IO 3 − ." @default.
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- W2334004853 date "2002-09-01" @default.
- W2334004853 modified "2023-10-17" @default.
- W2334004853 title "Uptake mechanism of IO<sub>3</sub> <sup>−</sup> to NO<sub>3</sub> <sup>−</sup>-hydrotalcite" @default.
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- W2334004853 doi "https://doi.org/10.1524/ract.2002.90.9-11_2002.671" @default.
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