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- W2334004940 endingPage "8486" @default.
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- W2334004940 abstract "Conjugated polymers with latent hydrogen-bonding on the main chain were synthesized using Suzuki coupling reaction. The resulting polymers with latent hydrogen-bonding can be converted to the actual hydrogen-bonded polymers by thermal annealing or UV irradiation. As the hydrogen-bonding sites are fused with π-conjugated units on the polymer backbone, the intermolecular interactions between the polymer chains will be strongly enhanced when the hydrogen-bonds are formed. By removing the protection group and forming hydrogen-bonding, the polymers exhibited a bathochromic shift over those with latent hydrogen-bonding, indicating a hydrogen-bonding-mediated enhancement of π–π stacking. In addition, the fused hydrogen-bond sites and π-conjugated units led to closely packed polymer chains, resulting in insoluble pigment-like polymers. This drastic solubility change from polymers with latent hydrogen-bonding to hydrogen-bonded polymers can be used to pattern conjugated polymers directly. The photolithography of the conjugated polymer with latent hydrogen-bonding was demonstrated, and the patterned electrochromic devices were fabricated and tested." @default.
- W2334004940 created "2016-06-24" @default.
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- W2334004940 date "2014-12-03" @default.
- W2334004940 modified "2023-09-25" @default.
- W2334004940 title "Patternable Conjugated Polymers with Latent Hydrogen-Bonding on the Main Chain" @default.
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- W2334004940 doi "https://doi.org/10.1021/ma501960t" @default.
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