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- W2334050248 abstract "An operationally simple, inexpensive, and rapid route for the olefination of a wide array of trifluoromethyl ketones to yield 3,3,3-trifluoromethylpropenes is reported. Using a Peterson olefination approach, the reaction gives good to excellent yields of the alkene products and can be performed without purification of the β-hydroxysilyl intermediate. The reaction can be extended to other perfluoroalkyl substituents and is easily scaled up. The alkenes prepared can be readily transformed into a variety of other perfluoroalkyl-containing compounds." @default.
- W2334050248 created "2016-06-24" @default.
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- W2334050248 date "2014-01-21" @default.
- W2334050248 modified "2023-10-11" @default.
- W2334050248 title "Methylenation of Perfluoroalkyl Ketones using a Peterson Olefination Approach" @default.
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- W2334050248 doi "https://doi.org/10.1021/jo402577n" @default.
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