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- W2334080396 abstract "One-electron oxidation of the ferrous tris-PQ complex, a model for lipoxygenase, was attempted using oxidants such as •OH, N•3, Br•-2, Tl2+ and TlOH+. •OH was found to react with the complex with a bimolecular rate constant of (3.9±0.6)x109dm3mol-1s-1, a rate which is not very dissimilar to that for the reaction with the ligand PQ. However the product of the reaction was found to be a OH-adduct rather than a cation radical. No reaction was found to occur with N•3 or Br•-2. Both Tl2+ and TlOH+ reacted with the complex to form its oxidised species with rate constants of (7.0±1)x108dm3mol-1s-1 and (4.0±0.8)x108dm3mol-1s-1, respectively. From a comparison of the rate constants and the transient spectra it was concluded that the centre of oxidation is the ligand rather than the metal." @default.
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- W2334080396 date "1993-10-01" @default.
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- W2334080396 title "One-electron oxidation of the iron(II) complex of 1,10-phenanthroline-5,6-quinone" @default.
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- W2334080396 doi "https://doi.org/10.1016/0969-806x(93)90418-t" @default.
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