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• W2334118835 abstract "We report a simple, rapid, and solvent-free methodology for solid-state polymerizations yielding poly(phenylene vinylenes) (PPVs) promoted by ball-milling. This solid-state Gilch polymerization method produces PPVs in as little as five minutes of milling. Detailed investigations of the parameter space governing the solid-state polymerization, i.e., milling time, base strength, solid-state dilution, milling frequency, and size of milling balls, revealed that polymerization by ball-milling is a rapid process achieving molecular number average weights of up to 40 kDa in up to 70% yield. To explore the scope, a solid-state polymerization via the dithiocarbamate precursor route is explored." @default.
• W2334118835 created "2016-06-24" @default.
• W2334118835 creator A5016748007 @default.
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• W2334118835 date "2014-03-17" @default.
• W2334118835 modified "2023-10-16" @default.
• W2334118835 title "Mechanochemical Synthesis of Poly(phenylene vinylenes)" @default.
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• W2334118835 doi "https://doi.org/10.1021/mz500098r" @default.
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